Carbon-nanotube-doped Pd-Ni bimetallic three-dimensional electrode for electrocatalytic hydrodechlorination of 4-chlorophenol: Enhanced activity and stability

Wu, Yifan; Gan, Ling; Zhang, Shupeng; Song, Haiou; Lu, Chang; Li, Wentao; Wang, Zheng; Jiang, Bicun; Li, Aimin

doi:10.1016/j.jhazmat.2018.05.034

Cited by 67 publications

(21 citation statements)

References 41 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…In addition, the electrodes prepared with an interlayer exhibited a much higher catalytic activity towards the dechlorination of 4-chlorophenol than those without interlayer [160]. Similar effects were reported with the utilization of various interlayers, such as carbon nanotubes [100,161], graphene-based materials [162][163][164], or titanium-based interlayers [165,166] (2) Component's molecular structure effect…”

Section: [ ] [ ]supporting

confidence: 56%

See 1 more Smart Citation

Metallic nanoparticles for electrocatalytic reduction of halogenated organic compounds: A review

Lou

Fontmorin

Amrane

et al. 2021

Electrochimica Acta

View full text Add to dashboard Cite

Section: [ ] [ ]supporting

confidence: 56%

“…Recently, increasing attention has been paid to bi-and tri-metallic NPs to obtain higher electrocatalytic property, resulting from the synergistic reaction between metals [98][99][100].…”

Section: Multi-metal Npsmentioning

confidence: 99%

Metallic nanoparticles for electrocatalytic reduction of halogenated organic compounds: A review

Lou

Fontmorin

Amrane

et al. 2021

Electrochimica Acta

View full text Add to dashboard Cite

“…197 Experimental parameters (e.g., pH value, applied current, electrolyte) also impact the performance of cathodes heavily. 185,198,199 Take the cathode potential as an example, Jiang et al 199 found that the applied potential had a great influence on the evolution of three different hydrogen species, namely adsorbed atomic hydrogen (H* ads ), absorbed atomic hydrogen (H* abs ), and molecular hydrogen (H 2 ). Combined with the degradation efficiency and kinetics of 2,4-Dichlorophenol (Fig.…”

Section: Pd-based Catalystsmentioning

confidence: 99%

Recent advances in electrocatalysts for halogenated organic pollutant degradation

Chen

Liu

Wei

et al. 2019

Environ. Sci.: Nano

View full text Add to dashboard Cite

show abstract

“…Therefore, Pd based bimetallic catalysts are considered as promising candidates for the degradation of different organic and environmental pollutants. For example, Pd/Au 45 , Pd/Ni 46 , Pd/Pt 44 and Pd/Cu 47 are investigated as prominent bimetallic materials for various applications.…”

Section: Introductionmentioning

confidence: 99%

Synthesis of bimetallic nanoparticles loaded on to PNIPAM hybrid microgel and their catalytic activity

Kakar

Khan

Akram

et al. 2021

Sci Rep

View full text Add to dashboard Cite

This study was designed to preparecarboxyl-functionalized poly (N-isopropylacrylamide) PNIPAM microgels having excellent catalytic properties.Recently, researchers are trying to fabricate cost effective and efficient hybrid catalytic materials for the synthesis of nitrogenous compounds along with enhanced optical properties. For the same motive, synthesis of carboxyl-functionalized PNIPAM microgels was performed by using polymerization of soap-free emulsion of N-isopropyl acrylamide, which is NIPAM along with acrylic acid (AA). The thiol group was introduced through the imide bond mediated by carbodiimide, between carboxyl-functionalized microgels through carboxyl group and aminoethanethiol (AET). Copper, Palladium and Cu/Pd nanoparticles were incorporated successfully into thiol-functionalized PNIPAM microgels through metals thiol linkage. The synthesized microgels and hybrid encompassing metallic nanoparticles were characterized in detail by using Transmission electron microscopy (TEM), Scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray photoelectron (XPS) and Fourier transformed infrared spectroscopy for structural interpretation. The thermal properties of the pure and hybrid microgels were inspected by TG analysis. The prepared nanocomposites PNIPAM-Cu, PNIPAM-Pd and PNIPAM-Cu/Pd exhibited decent catalytic properties for the degradation of 4-Nitrophenol and methylene blue, but the bimetallic Cu/Pd have remarkable catalytic properties. The catalytic reaction followed pseudo-first-order reaction with rate constants 0.223 min−1, 0.173 min−1 for 4-Nitrophenol and methylene blue in that order. In this study,we were able to establish that Cu/Pd hybrid is an efficient catalyst for 4-Nitrophenol and methylene blue as compared to its atomic analogue.

show abstract

Carbon-nanotube-doped Pd-Ni bimetallic three-dimensional electrode for electrocatalytic hydrodechlorination of 4-chlorophenol: Enhanced activity and stability

Cited by 67 publications

References 41 publications

Metallic nanoparticles for electrocatalytic reduction of halogenated organic compounds: A review

Metallic nanoparticles for electrocatalytic reduction of halogenated organic compounds: A review

Recent advances in electrocatalysts for halogenated organic pollutant degradation

Synthesis of bimetallic nanoparticles loaded on to PNIPAM hybrid microgel and their catalytic activity

Contact Info

Product

Resources

About