We demonstrate that low-pressure glow discharges in He-O 2 gas mixture are effective in removing carbonaceous surface layers from coked catalysts. These discharges contain a number of reactive species including O, O 3 , and O 2 *, and all these could contribute in the decoking process. However, an evolving understanding is that the O atoms in the discharge have a predominant role in this. A working hypothesis is that the O atoms react with the coke to form CO, CO 2 and other carbon complexes. Online measurements using emission spectra from O, H, and CO in the discharges are compared for the cases of He-O 2 and Ar-O 2 gas mixtures. Under the reported experimental conditions the estimated reactivity of the He-O 2 discharges is considerably higher compared with discharges in the Ar-O 2 gas mixture. Raman spectroscopy is used to confirm the removal of the coke from the surface of Pt/Alumina catalyst.