Carbonate-Catalyzed Reverse Water-Gas Shift to Produce Gas Fermentation Feedstocks for Renewable Liquid Fuel Synthesis

Abstract

Carbon-neutral liquid fuel generation is essential for decarbonizing sectors that cannot readily electrify. Recently commercialized acetogenic gas fermentation offers an alternative to conventional biofuels that circumvents efficiency limitations and land requirements, provided the requisite H2/CO feedstocks can be generated efficiently using renewable inputs. CO2 electrolysis to CO is under development for this purpose, but suffers from scalability challenges and impurity sensitivity. We describe an alternative that utilizes dispersed alkali carbonates as reverse water-gas shift (RWGS) catalysts to convert H2 and CO2 to an appropriate ratio of CO/CO2/H2 for acetogenic fermentation. Using a fixed bed reactor operating at industrially relevant space velocity, we demonstrate equilibrium RWGS conversion starting at 410 °C that remains stable over days, even with 50 ppm H2S impurity. The combination of carbonate-catalyzed RWGS, water electrolysis, and gas fermentation could convert electricity to ethanol with nearly 50% energy efficiency, providing a compelling option for renewable liquid fuel production.

Improving Carbonate-Promoted C–H Carboxylation Using Mesoporous Carbon Supports

“…Finally, we show that carbon supports can be used in multiple cycles of C–H carboxylation followed by methylation to transform (hetero)­arenes into methyl esters. The support effects on dispersed carbonate reactivity described here are important for advancing carbonate-promoted C–H carboxylation toward applications and provide insights that are valuable for other applications of dispersed carbonates such as reverse water-gas shift catalysis …”

“…The support effects on dispersed carbonate reactivity described here are important for advancing carbonate-promoted C−H carboxylation toward applications and provide insights that are valuable for other applications of dispersed carbonates such as reverse water-gas shift catalysis. 31 ■ RESULTS AND DISCUSSION Support materials were prepared following reported procedures with minor modifications (see Supporting Information for full details). A highly disordered mesoporous carbon (DMC) material was prepared by pyrolyzing magnesium citrate and removing the residual MgO with HCl.…”