Although charcoal production is a source of income, it is often associated with deforestation due to the felling of trees in rural areas. In this study, we quantified the yield of carbonization in the rural area of Lubumbashi, Democratic Republic of the Congo (DR Congo), and identified its determinants. By analyzing 20 kilns of professional producers in different villages, we found that these charcoal producers build large kilns, which contained an average of 46.9 ± 21.5 m3 of wood from 19 species of Miombo woodland trees, with a predominance of Julbernardia paniculata (Benth.) Troupin, alongside Brachystegia microphylla Harms and B. spiciformis Benth. The average carbonization yield was 10.2%, varying from village to village due to parameters such as kiln size, quantity of wood used, kiln coverage time, wind exposure, substrate type, and tree species. It was noted that the moisture content and dimensions of the wood did not significantly correlate with the quantity of charcoal harvested per kiln. Yield improvement should, therefore, take these parameters into account to enable charcoal producers to increase their income while adopting sustainable production practices.