Kirk-Othmer Encyclopedia of Chemical Technology 2000
DOI: 10.1002/0471238961.0301180223010714.a01
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Carbonyls

Abstract: Carbon monoxide forms a host of metal carbonyl complexes, at least one for every transition metal. Mononuclear, polynuclear, and heteronuclear metal carbonyls are all known. The complexes, of general formula M x (CO) y , may be charged or neutral; the metal or metals are in the zero oxidation state. Metal carbonyls are useful as reagents and catalysts in organic synthesis, and play a role in both the Reppe a… Show more

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