2020
DOI: 10.1002/ange.202010211
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Carboxyboronate as a Versatile In Situ CO Surrogate in Palladium‐Catalyzed Carbonylative Transformations

Abstract: The application of carboxy‐MIDA‐boronate (MIDA=N‐methyliminodiacetic acid) as an in situ CO surrogate for various palladium‐catalyzed transformations is described. Carboxy‐MIDA‐boronate was previously shown to be a bench‐stable boron‐containing building block for the synthesis of borylated heterocycles. The present study demonstrates that, in addition to its utility as a precursor to heterocycle synthesis, carboxy‐MIDA‐boronate is an excellent in situ CO surrogate that is tolerant of reactive functionalities s… Show more

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