Carboxylate-Based Metal–Organic Framework and Coordination Polymer Glasses: Progress and Perspectives

Abstract

Figure 4. (a) View of 4-fold interpenetrated dia-net CoL1 and the perturbation strategy to facilitate glass formation. (b) Thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) curves of p-CoL1 at a heating rate of 10 K/min under a N 2 atmosphere. (c) View of the coordination environment of the linear [Mn 3 ] node and the conformational change of the linker upon guest removal. (d) Temperature-dependent pathway of enthalpy during the desolvation process. Reproduced with permission from ref 45.