The asymptotic lifetime dependency on temperature, excitation depth and intensity, and on continuous-wave bias illumination have been investigated for the simultaneous determination of the recombination parameters to characterize neutron transmutation doped silicon by the microwave absorption transient technique. These experiments also reveal trapping effects. Defects, which are characterized by activation energies of 0.16 ± 0.02 eV, 0.20 ± 0.02 eV and 0.28 ± 0.04 eV, are controlling both bulk and surface recombination. The traps E C − 0.23 eV, E C − 0.28 eV and E C − 0.53 eV, which are revealed by deep-level transient spectroscopy, confirm the presence of these defects.