We present the results of nonequilibrium carrier dynamics in highly excited 4H-SiC crystals -n-type epilayers and semiinsulating wafer. Picosecond four-wave mixing measurements have been carried out at various grating periods, excitation energies, temperatures, and have provided the bipolar diffusion coefficients and lifetimes of nonequilibrium carriers. We show that the phonon scattering contributes mainly to the carrier mobility in 100-300 K temperature range, providing µ ∼ T −1.5 dependence. Lattice heating was observed, and it dominated in refractive index modulation at T < 100 K, thus precluding the studies of carrier dynamics at low temperatures.