We considered possibilities of an application of diffractive free-form optics in laser processing of metallic materials in aerospace production. Based on the solution of the inverse problem of heat conduction, an algorithm was developed that calculates the spatial distribution of the power density of laser irradiation in order to create the required thermal effect in materials. It was found that the use of diffractive optics for the laser beam shaping made it possible to obtain specified properties of processed materials. Laser thermal hardening of parts made of chrome–nickel–molybdenum steel was performed. This allowed us to increase the wear resistance due to the creation in the surface layer of a structure that has an increased hardness. In addition, a method of laser annealing of sheet materials from aluminum–magnesium alloy and low-alloy titanium alloys was developed. Application of this method has opened opportunities for expanding the forming options of these materials and for improving the precision in the manufacturing of aircraft engine parts. It was also shown that welding by a pulsed laser beam with a redistribution of power and energy density makes it possible to increase the strength of the welded joint of a heat-resistant nickel-based superalloy. Increasing the adhesion strength of gas turbine engine parts became possible by laser treatment using diffractive free-form optics.