Catalyst and catalytic mechanism for direct synthesis of cyclic carbonates by one-pot oxidative carboxylation of olefins and CO2

Wang, Huidong; Gao, Ziyu; Sun, Jianmin

doi:10.1016/j.mcat.2024.114417

Molecular Catalysis

2024

DOI: 10.1016/j.mcat.2024.114417

|View full text |Cite

Catalyst and catalytic mechanism for direct synthesis of cyclic carbonates by one-pot oxidative carboxylation of olefins and CO2

Huidong Wang,

Ziyu Gao,

Jianmin Sun

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2024

Publication Types

Select...

Article1

Relationship

Self Cite0

Independent1

Authors

Journals

Cited by 1 publication

References 62 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Molecular Architecture @ MOFs: Designing a Multifunctional Catalyst for the Cascade Reaction of Olefins via Epoxides to Cyclic Carbonates

Hemmer,

Hegelmann,

Fischer

et al. 2024

ChemCatChem

View full text Add to dashboard Cite

Employing enzymatic reaction cascade principles to synthesize artificial materials with multiple autonomously operating active sites is one of the holy grails in modern catalysis research. In this regard, metal‐organic frameworks (MOFs) are promising host platforms. Yet, applying MOFs as enzyme‐mimicking catalysts is synthetically challenging. Herein, we present a design strategy for the synthesis of porphyrin‐based MOFs for the cascade catalysis of the conversion of olefins to epoxides and their cycloaddition with CO2 to cyclic carbonates. The MOFs feature tunable dual active sites with synthetically controllable metal variations. A clear dependence of the metal combination on the catalytic performance of the MOF catalysts is shown. This work advances the understanding essential for designing sophisticated, multifunctional porphyrin MOFs for efficient one‐pot cascade catalysis.

show abstract

Molecular Architecture @ MOFs: Designing a Multifunctional Catalyst for the Cascade Reaction of Olefins via Epoxides to Cyclic Carbonates

Hemmer,

Hegelmann,

Fischer

et al. 2024

ChemCatChem

View full text Add to dashboard Cite

show abstract

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Catalyst and catalytic mechanism for direct synthesis of cyclic carbonates by one-pot oxidative carboxylation of olefins and CO2

Cited by 1 publication

References 62 publications

Molecular Architecture @ MOFs: Designing a Multifunctional Catalyst for the Cascade Reaction of Olefins via Epoxides to Cyclic Carbonates

Molecular Architecture @ MOFs: Designing a Multifunctional Catalyst for the Cascade Reaction of Olefins via Epoxides to Cyclic Carbonates

Contact Info

Product

Resources

About