Catalytic dry-reforming on Ni–zeolite supported catalyst

Frontera, Patrizia; Macario, Anastasia; Aloise, A.; Crea, F.; Antonucci, P.L.; Nagy, J.B.; Frusteri, F.; Giordano, G.

doi:10.1016/j.cattod.2011.07.039

Cited by 53 publications

(32 citation statements)

References 27 publications

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“…Calcination temperature (500-900°C) employed showed negligible effect on catalyst stability or activity, but both CH 4 and CO 2 conversions were favored by reaction temperature consistent with endothermic nature of the reaction as observed by other authors [142,143]. Table V summarizes recent literature data on the behavior of zeolite supports as reforming systems [144,[151][152][153][154]. Among the zeolite supports, ZSM-5 demonstrated the highest catalytic activity and stability.…”

Section: Effect Of Zeolite Catalystssupporting

confidence: 75%

A review on coke management during dry reforming of methane

Muraza

Galadima

2015

Int. J. Energy Res.

310

139

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Summary The dry (CO2) reforming of methane is a great promising technology, particularly because of its dual advantages of natural gas valorization and mitigating global warming via carbon dioxide sequestration. However, coke management is the most difficult problem in commercialization of the process. We have therefore examined in this paper the various catalytic systems being evaluated for the dry reforming with emphasis on operating parameters, activity, and coke deposition. Other factors such as the catalyst promoter, the reactor system, and the periodical regeneration were also critically reviewed. The benefits of utilizing methane from natural gas and other sources, where carbon dioxide is considered as an impurity component, are emphasized. Structured basic catalysts, with periodic regeneration certainties, are strong candidates for industrial applications. Therefore, efforts to build commercial scales for the benefit of global energy industries were highlighted. Copyright © 2015 John Wiley & Sons, Ltd.

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Section: Effect Of Zeolite Catalystssupporting

confidence: 75%

A review on coke management during dry reforming of methane

Muraza

Galadima

2015

Int. J. Energy Res.

310

139

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“…Thus, there is not too much difference in the nature of the coke deposited on NCA, NMA and NZA. However, NLA possesses distinct features compared to the other solids, judging from the largest amount of carbon deposition, especially inactive disordered whisker carbon species [2], as demonstrated by the lesser intensity of the G band, in comparison with the other solids. This is in good agreement with the minor catalytic performance of NLA.…”

Section: 3mentioning

confidence: 99%

Mesoporous catalysts for dry reforming of methane: Correlation between structure and deactivation behaviour of Ni-containing catalysts

Sousa

Silva

Castro

et al. 2012

International Journal of Hydrogen Energy

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“…The evidence reported in literature push one to think that a lower concentration of Lewis acid sites improves the catalytic capacity, and this is why the attention was focused on silicalite-1 (Frontera et al, 2012). This zeolite demonstrates good performance in other reactions that require low acidity (Bonelli et al, 2007).…”

Section: Solid Catalysts For Methane Dry Reforming In Traditional Andmentioning

confidence: 99%