Catalytic Effect of K2CO3 in Steam Gasification of Lignite Char on Mole Ratio of H2/CO in Syngas

Abstract

To fulfill the requirement for synthetic fuel (synfuel) production in theFischer-Tropsch process, in which syngas fed to the process has a H2/CO mole ratio approaching 2, gasification of lignite coal is needed. In this research, char particles were prepared by pyrolysis of lignite coal at controlled heating rates to obtain the highest possible surface area for gasification. In the gasification process, char with a surface area of 172.5 m 2 /g was used, along with the catalyst K2CO3 in a fixed bed reactor. In this research, there were variations in the steam/char mass ratio Results of this research showed that the highest H2/CO mole ratio of 2.07 corresponding to the mole ratio of gas yield/carbon of 1.13 was achieved at the gasification temperature of 675 o C using the catalyst K2CO3; the steam/char mass ratio was 2.0. However, at the same gasification conditions-but without a catalyst-the H2/CO mole ratio and corresponding mole ratio of gas yield/carbon were 3.02 and 0.42, respectively. A finding of this research was that the addition of the catalyst K2CO3 to gasification of lignite char adversely reduced the mole ratio of H2/CO compared to gasification without catalysis. It is suspected that the high composition of mineral ash in coal ash reacted with the K2CO3 catalyst, thus causing the Boudouard reaction to compete considerably with the water-gas reaction. The increases in gasification temperature and the steam/carbon ratio lowered the mole ratio of H2/CO in syngas.

Toward Low-Temperature Coal Gasification: Experimental and Numerical Studies of Thermochemical Coal Conversion Considering the Interactions between Volatiles and Char Particles

“…AAEM species are generally loaded on low rank coals using water-soluble precursors such as NaCl (Takarada et al, 1989;Wu et al, 2005), Na 2 NO 3 (Yamashita et al, 1991), Ca(NO 3 ) 2 (Ohtsuka and Tomita, 1986), CaCl 2 (Yamashita et al, 1992), Ca(CH 3 COO) 2 (Ohtsuka and Tomita, 1986;Tyler and Schafer, 1980), KCl (Liu and Zhu, 1986), or K 2 CO 3 (Liu and Zhu, 1986;Tristantini et al, 2015). Kajita et al (2010) reported that Na + and K + were irreversibly transferred from the char to the mineral matter (alumina) when contacting with each other at 800 °C.…”