Abstract:Enantioselective ring-opening reaction of meso-epoxides with arylselenols using a chiral (salen)Ti(IV) complex as catalyst was realized, and 1,2-arylseleno alcohols were obtained in good yields and up to 80 % ee.
We report the synthesis and structural characterization of two-dimensional {Co(3+)-Zn(2+)} and {Co(3+)-Cd(2+)} heterobimetallic networks and their catalytic applications in heterogeneous and solvent-free ring opening reactions of various epoxides.
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