Catalytic enhancement of platinum supported on zeolite beta for toluene hydrogenation by addition of palladium

Loiha, Sirinuch; Föttinger, Karin; Zorn, Katrin; Klysubun, Wantana; Rupprechter, Günther; Wittayakun, Jatuporn

doi:10.1016/j.jiec.2009.09.006

Cited by 36 publications

(16 citation statements)

References 20 publications

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“…Thus, we considered that the activated process did not damage the novel structure of the CNTs. However, the crystalline size of the ACNTs is smaller than that of CNTs as calculated using the Debye-Scherrer equation [27], which gives the ACNTs a higher specific surface area. For CuO/CNTs and CuO/ACNTs composites (Fig.…”

Section: Characterization Of Materialsmentioning

confidence: 97%

Synthesis of activated carbon nanotube/copper oxide composites and their electrochemical performance

Kim

Rhee

Park

2012

Journal of Alloys and Compounds

139

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Section: Characterization Of Materialsmentioning

confidence: 97%

Synthesis of activated carbon nanotube/copper oxide composites and their electrochemical performance

Kim

Rhee

Park

2012

Journal of Alloys and Compounds

139

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“…The silicon to aluminum ratio in zeolite beta has been varied greatly, and lower Si/Al ratios have been found to favor a faster crystallization rate [1]. Pt and Pd loaded zeolites have been used for the selective hydrogenation of toluene with complete conversion and 100% selectivity under optimal conditions [2]. Modhera and coworkers studied hydroisomerization of 1-hexene over platinum loaded nanocrystalline zeolite-beta [3].…”

Section: Introductionmentioning

confidence: 99%

From nanoparticles to hierarchical structures: Controlling the morphology of zeolite beta

Петушков

Merilis

Larsen

2011

Microporous and Mesoporous Materials

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“…Supported noble metals hydrogenation catalysts are highly expensive with high vulnerability to sulfur poisoning; this led to a declined interest in their use in a conventional hydrogenation process. Transition metals of group VI (Mo, W) are also reported to be effective hydrogenation catalyst [3][4][5]. They are less expensive and exhibit high resistance to sulfur poisoning.…”

Section: Introductionmentioning

confidence: 99%

Hydrogenation of toluene on Ni-Co-Mo supported zeolite catalysts

Shuwa¹,

Jibril²,

Al‐Hajri³

2018

Nig. J. Tech.

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Mixed oxides of Ni, Co and Mo supported on five zeolites -ZSM-5-a, ZSM-5-b, HY-a, HY-b and Mordenite were prepared and characterized using many techniques for use as hydrotreating catalysts. In a preliminary investigation, toluene was employed as model compound to test the catalysts in hydrogenation, as a major upgrading reaction. TGA/DSC analysis showed that the impregnation of the metals slightly affected the thermal stability of the zeolites with all catalytic samples displaying good stability up to 730 o C.The XRD patterns for all the catalytic samples showed that the framework of the zeolites were retained after impregnation. XRD and TPR results confirmed the presence of molybdenum trioxide on the zeolites with NiCoMo/HY-b displaying high metal-support interaction due to low reduction temperatures. The activity results showed that toluene conversion of almost 100% and selectivity to mainly methyl-cyclohexane was achieved. The catalysts activity test showed that the zeolite support textural properties particularly surface area, pore volume and pore diameter affect the performance of the catalysts. NiCoMo/HY-b displayed the best performance after the few minutes of the reaction due to its high surface area, pore volume and average pore diameter.

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Catalytic enhancement of platinum supported on zeolite beta for toluene hydrogenation by addition of palladium

Cited by 36 publications

References 20 publications

Synthesis of activated carbon nanotube/copper oxide composites and their electrochemical performance

Synthesis of activated carbon nanotube/copper oxide composites and their electrochemical performance

From nanoparticles to hierarchical structures: Controlling the morphology of zeolite beta

Hydrogenation of toluene on Ni-Co-Mo supported zeolite catalysts

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