Catalytic oxidation of 5-hydroxymethylfurfural into 2,5-diformylfuran using V-containing heteropoly acid catalysts

Rodikova, Yulia A.; Жижина, Е. Г.

doi:10.1007/s11144-020-01782-z

Cited by 18 publications

(4 citation statements)

References 28 publications

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“…V-based heteropoly acid salts (PMoV HPAs) [47] have also been used as catalysts in the reaction of HMF to DFF. The fundamental component of the reaction was still found as the V 5 + /V 4 + cycle, and different metal oxides (such as CeO 2 ) were used as carriers.…”

Section: R E V I E W T H E C H E M I C a L R E C O R Dmentioning

confidence: 99%

Recent Progress in Metal‐Catalyzed Selective Oxidation of 5‐Hydroxymethylfurfural into Furan‐Based Value‐Added Chemicals

Zhang

Chen

et al. 2023

The Chemical Record

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5‐hydroxymethylfurfural (HMF), one of the most significant biomass‐derived renewable resources, has been widely utilized to create furan‐based value‐added chemicals such as 2,5‐diformylfuran (DFF), 5‐hydroxymethyl‐2‐furancarboxylic acid (HMFCA), 5‐formyl‐2‐furancarboxylic acid (FFCA), and 2,5‐furan dicarboxylic acid (FDCA). Indeed, DFF, HMFCA and FFCA are key intermediate products during the oxidation of HMF to FDCA. Herein, this review aims to demonstrate the recent advances in metal‐catalyzed oxidation of HMF into FDCA via two different reaction routes (HMF‐DFF‐FFCA‐FDCA and HMF‐HMFCA‐FFCA‐FDCA). All the four furan‐based compounds are comprehensively discussed by the selective oxidation of HMF. Additionally, various metal catalysts, reaction conditions, and reaction mechanisms used to obtain the four different products are systematically reviewed. It is anticipated that this review will provide related researchers with new perspectives and speed up the development of this field.

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Section: R E V I E W T H E C H E M I C a L R E C O R Dmentioning

confidence: 99%

Recent Progress in Metal‐Catalyzed Selective Oxidation of 5‐Hydroxymethylfurfural into Furan‐Based Value‐Added Chemicals

Zhang

Chen

et al. 2023

The Chemical Record

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“…Alternatively, the advantages of transition metals are well known; however, vanadium, which is commonly used in the oxidation of HMF, undergoes a loss of its active components during the reaction, and so tends to be employed in combination with other elements. ( Navarro et al, 2009 ; Rodikova and Zhizhina, 2020 ). In this context, Zhao et al synthesized a catalyst based on vanadium dioxide (VO 2 )-embedded mesoporous carbon spheres (V-CS) using a facile hydrothermal method, which produced DFF in a yield of 99.0% ( Zhao et al, 2018 ).…”

Section: Introductionmentioning

confidence: 99%

Production of the 2,5-Furandicarboxylic Acid Bio-Monomer From 5-Hydroxymethylfurfural Over a Molybdenum-Vanadium Oxide Catalyst

et al. 2022

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2, 5-Furandicarboxylic acid (FDCA) is an important bio-monomer that can potentially replace terephthalic acid to synthesize degradable polyesters. Efficient selective oxidation of biomass-based 5-hydroxymethylfurfural (HMF) to FDCA has been a significant but challenging work in the past decades. In this study, a novel molybdenum-vanadium oxide (Mo-V-O) catalyst was prepared by a simple method and showed excellent catalytic activity for converting HMF to FDCA. A high FDCA selectivity of 94.5 and 98.2% conversion of HMF were achieved under the optimal conditions with tert-butyl hydroperoxide as the oxidant. FT-IR, SEM, XRD and TG were applied to investigate the properties of Mo-V-O catalyst. After fitting experimental data with the first-order kinetics equation, the evaluated apparent activation energies of HMF oxidation were obtained. The experimental design and study were carried out by response surface methodology (RSM) to test the effects of reaction conditions on the catalytic process.

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“…HPCs are used in photocatalysis [4,5], biochemistry and pharmacology [6][7][8]. The special role of HPCs as catalysts of various chemical reactions, mainly associated with oxidation processes [9,10] and, in particular, desulfurization [11][12][13], should be noted. In connection with the industrial importance of HPCs, the scienti c direction aimed at the synthesis of new heteropoly compounds has become widespread [13][14][15].…”

Section: Introductionmentioning

confidence: 99%

Application of laser desorption/ionization for investigation of phosphomolybdic acid

Minenkova

Emel’yanov

Tarkhanova

et al. 2022

Preprint

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Heteropoly compounds are of great practical importance as components of catalysts. In particular, phosphomolybdic acid H3PMo12O40 is widely used in catalytic oxidation processes. For heterogeneous catalysts, one of the effective methods for studying their structure is mass spectrometry. In this work, the main patterns of fragmentation of crystalline phosphomolybdic acid and its aqueous solutions are studied by laser desorption/ionization. It has been found that during laser desorption/ionization, acid crystals tend to form particles of the cluster type (MoO3)n and HPO3∙(MoO3)n. When registering positive ions, particles with a mixed oxidation state of Mo+ 5 and Mo+ 6 were detected. Clusters of molybdenum (VI) oxide were found in the study of aqueous solutions of acid. In the study of aqueous solutions together with a matrix of 2,5-dihydroxybenzoic acid, particles containing a hydrated molecular ion were found. Clusters with a molecular ion were identified: H3PMo12O40∙(MoO3)3, H3PMo12O40∙(MoO3)4, H3PMo12O40∙MoO3∙4H2O, H3PMo12O40∙(MoO3)2∙2H2O, H3PMo12O40∙(MoO3)2∙4H2O, and H3PMo12O40∙(MoO3)3∙2H2O. When studying the influence of the LDI parameters on the informativity of the mass spectrum, it was found that, in the general case, the values of the peak intensity and the laser power, as well as the number of shots, are in symbatic dependence. The intensity of the peak depends largely on the power of the laser than on the number of shots. Thus, it has been shown that, upon ionization, phosphomolybdic acid can generate both fragments and cluster ions containing mainly the adduct of the molecular ion with molybdenum oxide and water.

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Catalytic oxidation of 5-hydroxymethylfurfural into 2,5-diformylfuran using V-containing heteropoly acid catalysts

Cited by 18 publications

References 28 publications

Recent Progress in Metal‐Catalyzed Selective Oxidation of 5‐Hydroxymethylfurfural into Furan‐Based Value‐Added Chemicals

Recent Progress in Metal‐Catalyzed Selective Oxidation of 5‐Hydroxymethylfurfural into Furan‐Based Value‐Added Chemicals

Production of the 2,5-Furandicarboxylic Acid Bio-Monomer From 5-Hydroxymethylfurfural Over a Molybdenum-Vanadium Oxide Catalyst

Application of laser desorption/ionization for investigation of phosphomolybdic acid

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