Catalytic oxidation of cyclohexane to cyclohexanone and cyclohexanol by oxygen in a solvent-free system over metal-containing ZSM-5 catalysts

Catalytic Properties of Alumina-Supported Ruthenium, Platinum, and Cobalt Nanoparticles towards the Oxidation of Cyclohexane to Cyclohexanol and Cyclohexanone

“…The distribution of cyclohexanol and cyclohexanone shows no formation of cyclohexanone at 25 and 45 °C, and a temperature increase clearly favors the production of cyclohexanone. A similar behavior was noted by Zhou et al [5], and Yuan et al [41]. These results show that when the temperature increased from 25 to 70 °C, the conversion and selectivity towards cyclohexanone and cyclohexanol increased and The second order plots gave a straight line, indicating that the reaction is of the 2 nd order, as shown in Figure 6.…”

Solution and diffusion properties of cyclohexane, cyclohexanol, and cyclohexanone in poly(ethylene glycol) by inverse gas chromatography

“…[1][2][3][4] Among them, the selective oxidation of cyclohexane to cyclohexanol and cyclohexanone is very important reaction for commercial application. [5][6][7] Cyclohexanol and cyclohexanone are important organic intermediates in the petrochemical industry for the manufacture of caprolactam, nylon, and other products. 6 However, since cyclohexanol and cyclohexanone molecules are more reactive in oxidation than cyclohexane, their overoxidation prevents the selective synthesis at higher cyclohexane conversion.…”

“…[5][6][7] Cyclohexanol and cyclohexanone are important organic intermediates in the petrochemical industry for the manufacture of caprolactam, nylon, and other products. 6 However, since cyclohexanol and cyclohexanone molecules are more reactive in oxidation than cyclohexane, their overoxidation prevents the selective synthesis at higher cyclohexane conversion. 3,4 In the present industrial technology, the conversion of this reaction is always controlled about 3-10% for keeping higher selectivity.…”

“…3,4 In the present industrial technology, the conversion of this reaction is always controlled about 3-10% for keeping higher selectivity. Therefore, the reaction mixture contains a large amount of cyclohexane (about 95%), [4][5][6][7] and the industrial separation requires a three-step distillation. 4 Up to now, this technology suffers from low product efficiency, high investment, and energy consumption.…”

Oxidation of Cyclohexane to Cylohexanol and Cyclohexanone Over H₄[a-SiW₁₂O₄₀]/TiO₂ Catalyst

“…On the other hand, the reaction used soluble copper catalyst resulted homogeneous system with mild operated conditions oxidized cyclohexane [4]. Mesoporous materials such Oxidation of cyclohexane to cyclohexanol and cyclohexanone [4] as MCM-41, SBA, and ZMS were efficient catalyst for oxidation of cyclohexane to cyclohexanol in heterogeneous system and catalyst can be regenerated [5][6][7]. Complex of coordination compounds also shows catalytic activity oxidation of cyclohexane [8].…”