“…Equation 1 defines the mercury oxidation efficiency of these catalysts, and the detail of in this equation was listed in references [18,24,29,30]. The other reason that equation 1 was defined as the mercury oxidation efficiency was that nearly all the change in the elemental mercury concentration was existed in the form of oxidized mercury (including oxidized mercury released to the flue gas and mercury oxidized on the catalyst surface), and the detail discussion was listed in part 3.2.…”
Section: Experimental Conditionsmentioning
confidence: 99%
“…Subsequently, the manganese oxide with a low valence would be re-oxidized to a high valence in the presence of O 2 . Equation 1 to equation 4 are the main process [16,30].…”
Section: The Influence Of Hcl On Mercury Oxidized By Mn/cntmentioning
“…Equation 1 defines the mercury oxidation efficiency of these catalysts, and the detail of in this equation was listed in references [18,24,29,30]. The other reason that equation 1 was defined as the mercury oxidation efficiency was that nearly all the change in the elemental mercury concentration was existed in the form of oxidized mercury (including oxidized mercury released to the flue gas and mercury oxidized on the catalyst surface), and the detail discussion was listed in part 3.2.…”
Section: Experimental Conditionsmentioning
confidence: 99%
“…Subsequently, the manganese oxide with a low valence would be re-oxidized to a high valence in the presence of O 2 . Equation 1 to equation 4 are the main process [16,30].…”
Section: The Influence Of Hcl On Mercury Oxidized By Mn/cntmentioning
“…As stated above, there have been many studies focusing on the MnO x -based supported catalysts for Hg 0 oxidation at low temperature [13,15,18,[27][28][29][30]. For comparison, the Hg 0 oxidation activity of the MSCR-II in the present work, the MnO x supported on the carbon nanotube (Mn/CNT) [15] in our previous study and that reported in the literature are summarized in Fig.…”
Section: Performance Of Hg 0 Oxidation Over the Catalystsmentioning
“…6. The CeTi sorbent after adsorption significantly released mercury from 250-280 o C. No obvious Hg 2+ was observed during the entire regeneration process, indicating that mercury compounds were decomposed at high temperatures [22,23]. Note that a desorption peak was also detected at temperatures lower than 200 o C, which could be due to the release of weakly bound mercury species [24,25].…”
The characteristics of mercury desorption on spent CeO 2 -TiO 2 (CeTi) sorbents were investigated to improve the cyclic regeneration removal activity. Mercury was significantly released in the form of elemental mercury at temperatures ranging from 250 to 280 o C. Mercury desorption had a significant correlation with regeneration temperature, but was independent of the heating rate and regeneration conditions. The optimal regeneration temperature was 500 o C. The CeTi sorbents could be easily restored by simple heating and exhibited superior activity over several capture-regeneration cycles. The amount of released mercury almost equaled the adsorbed mercury on the surface of the CeTi sorbent, indicating that most of the adsorbed mercury was released during the heating process.
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