Catalytic ozonation of the antibiotic sulfadiazine: Reaction kinetics and transformation mechanisms

Kråkström, Matilda; Saeid, Soudabeh; Tolvanen, Pasi; Salmi, Tapio; Eklund, Patrik; Krönberg, Leif

doi:10.1016/j.chemosphere.2020.125853

Cited by 37 publications

(10 citation statements)

References 38 publications

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“…AOPs include in situ generation of very reactive oxygen species (ROS) by small selectivity, for example, superoxide anion radicals (O 2 − ), H 2 O 2 , O 3 and hydroxyl radicals (HO), with wide-ranging degradation to CO 2 , H 2 O and inorganic ions or acids (Dalrymple et al 2007;Kanakaraju et al 2018). Combining ozonation with catalysis have been used to enhance the removal of antibiotics and their products (Nawrock and Kasprzyk-Hordern 2010; Kråkström et al 2020). Catalysts used in combination with ozonation can be either homogenous or heterogeneous.…”

Section: Introductionmentioning

confidence: 99%

Catalytic ozonation for removal of antibiotic oxy-tetracycline using zinc oxide nanoparticles

Mohsin

Mohammed

2021

Appl Water Sci

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The traditional wastewater treatment plants are mostly not designed to deal with polar micropollutants such as pharmaceuticals. Therefore, antibiotics must be completely removed before their emission to ecosystems. Catalytic ozonation is used to increase the efficiency of sole ozonation further. In the present study, semi-batch experiments were conducted to investigate the efficiency of sole ozonation and catalytic ozonation in the degradation of oxy-tetracycline (OTC) as an environmental hazards contaminant in an aqueous solutions. Zinc oxide nanoparticles (ZnO) were used as a catalytic agent with ozone (ZnO/$${\mathrm{O}}_{3})$$ O 3 ) . The influence of operational parameters such as pH (3–11), initial oxy-tetracycline concentration (10–100) mg/l, temperature (15–35)°C, ozone generation rate (0.138–1.38)mg/s and catalyst dosage (25–200) mg/l on the ZnO/$${\mathrm{O}}_{3}$$ O 3 process was investigated. Ozone dosage was found to have the noticeable effect on the degradation process; however, the ZnO dosage was found to be less effective. The optimum condition was 1.38 mg/s at pH = 7, and after 35 min, a 94% of OTC removal was achieved. The results demonstrated that catalytic ozonation was a very effective method for degradation and mineralization of OTC in aqueous solution.

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Section: Introductionmentioning

confidence: 99%

Catalytic ozonation for removal of antibiotic oxy-tetracycline using zinc oxide nanoparticles

Mohsin

Mohammed

2021

Appl Water Sci

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“…1 They are widely used in the treatment of human and animal diseases and in aquaculture and livestock breeding. 2 In recent years, the use of antibiotics has greatly increased. According to statistics, the global daily consumption of antibiotics has increased from 21.1 billion in 2000 to 34.8 billion in 2015.…”

Section: Introductionmentioning

confidence: 99%

“…Antibiotics are secondary metabolites or synthetic analogues produced by some microorganisms that can inhibit the growth of other microorganisms at lower concentrations . They are widely used in the treatment of human and animal diseases and in aquaculture and livestock breeding . In recent years, the use of antibiotics has greatly increased.…”

Section: Introductionmentioning

confidence: 99%

Continuous Catalytic Ozonation of Antibiotics Using Mn and Cu Oxides on γ-Al₂O₃ Pellets in a Micropacked Bed Reactor

et al. 2021

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Today, the Al2O3-supported catalyst in the heterogeneous catalytic ozonation system attracts attention due to its stable structure and relatively high surface activity. Herein, Mn and Cu oxides loaded on γ-Al2O3 pellets were prepared using an impregnation method to improve the removal efficiency in a micropacked bed reactor (μPBR). The effects of the initial pH, the ratio of O3 to chemical oxygen demand (COD), and HO• scavenger on the catalytic performance were investigated. Experimental results showed that the MnO2/γ-Al2O3 and CuO/γ-Al2O3 catalysts exhibited excellent catalytic performance. The COD removal efficiencies were 86.3% for CuO/Al2O3, 76.9% for MnO2/Al2O3, 71.6% for Al2O3, and 35.8% for ozone alone within 71 s. Compared with those of batch reactors, the apparent degradation rate constant of COD with prepared catalysts in a μPBR increased by 2–3 orders of magnitude. In addition, the CuO/γ-Al2O3 catalyst maintained a relatively stable activity in the continuous flow test for a long time (100 h). Finally, some typical antibiotics were treated by catalytic ozonation in a μPBR. The removal efficiencies of these antibiotics and COD reached approximately 100.0% and 62.9–87.8% within 71 s, respectively. Thus, the continuous catalytic ozonation system with the CuO/γ-Al2O3 catalyst based on μPBRs could be a promising pathway for the treatment of industrial wastewater with antibiotics.

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“…Among them, sulfadiazine (SFZ) is one of the common sulfonamide antibacterial agents used in veterinary and human medicines to control infectious diseases. − The improper discharge of SFZ is the main cause of pollution to the environment mainly for ecosystems . The overexposure of SFZ can cause adverse physiological and biochemical conditions, such as liver damage, chronic toxicity, antibiotic resistance, gene damage, and high toxicity in all living organisms. , Maximum permissible levels for SFZ residues in aquatic systems in China range from 0.014 to 0.28 μg/L. , Following international regulation, the maximum allowable concentration of SFZ in milk is 0.07 ppm . Thus, the facile and rapid quantification of trace-level SFZ in the real-world samples has gained increasing interest.…”

Section: Introductionmentioning

confidence: 99%

“…4 The overexposure of SFZ can cause adverse physiological and biochemical conditions, such as liver damage, chronic toxicity, antibiotic resistance, gene damage, and high toxicity in all living organisms. 5,6 Maximum permissible levels for SFZ residues in aquatic systems in China range from 0.014 to 0.28 μg/L. 7,8 Following international regulation, the maximum allowable concentration of SFZ in milk is 0.07 ppm.…”

Section: ■ Introductionmentioning

confidence: 99%

Design and In Situ Synthesis of Titanium Carbide/Boron Nitride Nanocomposite: Investigation of Electrocatalytic Activity for the Sulfadiazine Sensor

Kokulnathan

Kumar

Wang

2020

ACS Sustainable Chem. Eng.

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Two-dimensional (2D) nanomaterials are considered a rising star in diverse electrochemical technologies due to their special characteristics. We report here the design and synthesis of 2D titanium carbide/boron nitride nanocomposite via the sonochemical method. The successfully produced TiC/BN nanocomposites were characterized by in-depth electron microscopic and spectroscopic methods and served as an electrocatalyst for the determination of sulfadiazine (SFZ). The good electrocatalytic activity toward SFZ sensing with strong durability and good stability can be achieved by the TiC/BN-modified electrode. The unique structural characteristic of the TiC/BN electrocatalyst is in favor of accommodating more surface sites, improved conductivity, promoted charge-transfer ability, and enhanced surface area. For the proof of the above concept, the TiC/BN-modified electrode was characterized with low charge-transfer resistance (R ct = 20 Ω), good peak potential separation (ΔE p = 0.080 V), and good active surface area (A = 0.106 cm2). According to the measurement results of electrochemical response toward SFZ, the TiC/BN-modified electrode shows a trace-level limit of detection (3.0 nM), a large working range (0.01–44; 59–186 μM), good sensitivity (1.47 μA μM–1 cm2), high selectivity and good reproducibility (4.11%). The proposed electrochemical sensor possesses good detection performance in monitoring human urine samples. The obtained results would shed light on the applications of electrocatalyst in electrochemical sensors.

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Catalytic ozonation of the antibiotic sulfadiazine: Reaction kinetics and transformation mechanisms

Cited by 37 publications

References 38 publications

Catalytic ozonation for removal of antibiotic oxy-tetracycline using zinc oxide nanoparticles

Catalytic ozonation for removal of antibiotic oxy-tetracycline using zinc oxide nanoparticles

Continuous Catalytic Ozonation of Antibiotics Using Mn and Cu Oxides on γ-Al₂O₃ Pellets in a Micropacked Bed Reactor

Design and In Situ Synthesis of Titanium Carbide/Boron Nitride Nanocomposite: Investigation of Electrocatalytic Activity for the Sulfadiazine Sensor

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Catalytic ozonation of the antibiotic sulfadiazine: Reaction kinetics and transformation mechanisms

Cited by 37 publications

References 38 publications

Catalytic ozonation for removal of antibiotic oxy-tetracycline using zinc oxide nanoparticles

Catalytic ozonation for removal of antibiotic oxy-tetracycline using zinc oxide nanoparticles

Continuous Catalytic Ozonation of Antibiotics Using Mn and Cu Oxides on γ-Al2O3 Pellets in a Micropacked Bed Reactor

Design and In Situ Synthesis of Titanium Carbide/Boron Nitride Nanocomposite: Investigation of Electrocatalytic Activity for the Sulfadiazine Sensor

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Continuous Catalytic Ozonation of Antibiotics Using Mn and Cu Oxides on γ-Al₂O₃ Pellets in a Micropacked Bed Reactor