2010
DOI: 10.1039/c002910f
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Catalytic production of hydrogen from glucose and other carbohydrates under exceptionally mild reaction conditions

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Cited by 61 publications
(49 citation statements)
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“…After a pioneering study in 1980 [11], the attention was more recently focused mostly on the PR of methanol, the simplest molecule, and a few examples of PR of compounds really obtainable from biomass can be found, for example, ethanol, glycerol [12][13][14], glucose, sucrose [14], starch and wood [11], and sewage sludge [15]. Glucose and cellulose were also processed with homogeneous catalytic processes [16]. Interestingly, biomass-derived substrates, such as alcohols or carbohydrates, may be used for hydrogen production particularly in the case of waste materials (sewage from food, wine, or paper industry) [17], simultaneously helping to clean wastes (without disposal costs) and to produce a highly valued fuel [18].…”
Section: Introductionmentioning
confidence: 99%
“…After a pioneering study in 1980 [11], the attention was more recently focused mostly on the PR of methanol, the simplest molecule, and a few examples of PR of compounds really obtainable from biomass can be found, for example, ethanol, glycerol [12][13][14], glucose, sucrose [14], starch and wood [11], and sewage sludge [15]. Glucose and cellulose were also processed with homogeneous catalytic processes [16]. Interestingly, biomass-derived substrates, such as alcohols or carbohydrates, may be used for hydrogen production particularly in the case of waste materials (sewage from food, wine, or paper industry) [17], simultaneously helping to clean wastes (without disposal costs) and to produce a highly valued fuel [18].…”
Section: Introductionmentioning
confidence: 99%
“…Some strongly solvating ILs are suitable to dissolve these (in classical solvents hardly soluble) materials. Thus, these substrates become accessible for homogeneous dehydrogenation [63]. Studies about the dehydrogenation of these carbohydrates revealed that e.g.…”
Section: Functionalized Ils For Catalytic Decom-position Of Formic Acidmentioning
confidence: 99%
“…Thermal decomposition pathway of glucose and subsequent catalytic splitting of formic acid in IL. (Taccardi et al, 2010) The thermal stability of the employed IL is remarkable and important in this application.…”
Section: Functionalized Ils For Catalytic Decomposition Of Formic Acidmentioning
confidence: 99%
“…Different ILs can be employed to solvate the carbohydrate feedstock and the [(p-Cymene)RuCl2]2 complex (-precursor) is suitable for dehydrogenation. (Taccardi et al, 2010) Detailed investigations by Wasserscheid et al showed that this reaction proceeds via the thermal decomposition of glucose to formic acid and subsequent catalytic decomposition of formic acid by the Ru complex. Some ILs, in this case for example 1-ethyl-3-methylimidazolium methyl-methylphosphonate, are able to solute wood.…”
Section: Functionalized Ils For Catalytic Decomposition Of Formic Acidmentioning
confidence: 99%