Catalytic properties of the vanadium-molybdenum oxide system for acrolein oxidation

Андрушкевич, Т. В.; Plyasova, L. M.; Kuznetsova, G. G.; Бондарева, В. М.; Gorshkova, T. P.; Olenkova, I. P.; Lebedeva, N. I.

doi:10.1007/bf02061755

Cited by 38 publications

(11 citation statements)

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“…Quantities of carbonaceous species up to 30 wt.% can be deposited during glycerol dehydration catalyzed by an acid zeolite with MFI structure [11]. A c c e p t e d M a n u s c r i p t 3 For the second step of Scheme 1, a redox catalyst is needed. Vanadium oxides have a very important redox characteristic in catalysis due to the capacity to adopt multiple oxidation states.…”

Section: Scheme 1 -Pathway Of the Glycerol Oxidehydration Reactionmentioning

confidence: 99%

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One-step glycerol oxidehydration to acrylic acid on multifunctional zeolite catalysts

Possato

Cassinelli

Garetto³

et al. 2015

Applied Catalysis A: General

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Section: Scheme 1 -Pathway Of the Glycerol Oxidehydration Reactionmentioning

confidence: 99%

“…In the first step, glycerol is dehydrated to 3-hydroxypropanal, a very reactive intermediate that readily dehydrates to give acrolein [1]. The second step is the selective oxidation of acrolein in the presence of molecular oxygen to yield acrylic acid [3][4][5][6][7].…”

Section: Introductionmentioning

confidence: 99%

One-step glycerol oxidehydration to acrylic acid on multifunctional zeolite catalysts

Possato

Cassinelli

Garetto³

et al. 2015

Applied Catalysis A: General

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“…The two major reasons that rendered this process unattractive were the price and availability of acetylene, and the toxicity and the corrosive nature of the homogeneous catalyst. The oxidation of propene to acrylic acid is generally carried out in two stages, namely the oxidation of propene to acrolein over the classical SOHIO bismuth-molybdate system [174], or multicomponent catalysts based on mixed metal oxide catalyst systems, composed of Mo − Bi − Fe − Co − W − O (e.g., the Nippon Shokubai catalyst system: [175]) in the first stage, followed by the oxidation of acrolein to acrylic acid over Mo − V − W − O mixed oxides (e.g., the BASF system [176], the original catalyst system from Distillers [177] and the system evolving from the studies of Andrushkevich [178]), which will be discussed later in the framework of the Mo − V − Nb − Te − O mixed oxides for direct conversion of propane to acrylic acid. The oxidation of propene to acrylic acid is generally carried out in two stages, namely the oxidation of propene to acrolein over the classical SOHIO bismuth-molybdate system [174], or multicomponent catalysts based on mixed metal oxide catalyst systems, composed of Mo − Bi − Fe − Co − W − O (e.g., the Nippon Shokubai catalyst system: [175]) in the first stage, followed by the oxidation of acrolein to acrylic acid over Mo − V − W − O mixed oxides (e.g., the BASF system [176], the original catalyst system from Distillers [177] and the system evolving from the studies of Andrushkevich [178]), which will be discussed later in the framework of the Mo − V − Nb − Te − O mixed oxides for direct conversion of propane to acrylic acid.…”

Section: Conversion Of Butane To Maleic Anhydride: An Overview Of a Mmentioning

confidence: 99%

Oxyfunctionalization of Alkanes

Schunk

2008

Handbook of Heterogeneous Catalysis

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The sections in this article are Introduction Analyzing the Challenge of Heterogeneously Catalyzed Alkane Oxidation Analysis on a Microscopic Basis of the Critical Steps of Paraffin Oxidation Utilizing Solid Catalysts Utilizing Solid Catalysts A Activation of Oxygen and Paraffin B Models for the Active Site C The Role of Co ‐Feeds in the Educt Stream D The Role of the Crystalline Nature and the Admixture of Different Crystalline Phases for the Catalyst E The Role of the Acid–Base Interaction of Reactant and Catalyst Analysis of the Technical Challenges of Paraffin Oxidation Utilizing Solid Catalysts Conversion of Butane to Maleic Anhydride: An Overview of a Mature Technology Manufacturing Technologies for MA from n ‐Butane The VPO ‐Catalyst: Structural Basis and Synthetic Pathways The VPO ‐Catalyst: Reaction Pathways and Potential Active Sites of the Catalyst Propane Oxidation to Acrylic Acid and Acrylonitrile: Getting Closer to a Technical Solution Rutile‐Based Structures for Selective Propane Oxidation Complex Bronze Structures Based on Molybdenum for Selective Propane Oxidation Ethane to Acetic Acid: The Search for a Viable Pathway Outlook Acknowledgments

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“…For example, the best catalytic properties for the selective oxidation of acrolein were reported for a mixture of MoO 3 with 7-15% V 2 O 4 , which was suggested to exhibit the Mo 3 VO 11 -structure with the formal stoichiometry of Mo 0.75 V 0. 25 O 2.75 [7][8][9]. These MoVW mixed oxide catalysts have been improved over the years by adding more and more promoters [10][11][12][13][14][15][16][17][18][19].…”

Section: Introductionmentioning

confidence: 99%

MoVW mixed metal oxides catalysts for acrylic acid production: from industrial catalysts to model studies

Mestl¹

2006

Top Catal

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MoVW) 5 O 14 -type oxides were identified as the active and selective components in industrial acrylic acid catalysts. Tungsten is suggested to play an important role as a structural promoter in the formation and stabilization of this oxide. Vanadium is responsible for high catalytic activities but is detrimental for the stability of this oxide at the necessary high concentrations for optimum catalytic performance. The activity of mixed MoVW oxide catalysts for methanol, propene, and acrolein partial oxidation could be considerably improved, when the amount of the (MoVW) 5 O 14 -type oxide was increased by thermal annealing. A model is proposed on the basis of the correlation between Raman wavenumber and bond order and degree of reduction, which explains the observed different selectivities of MoO 3)x and the (MoVW) 5 O 14 -type oxides in terms of metal-oxygen bond strengths, i.e. oxygen basicity and oxygen lability, respectively. According to this model, the (MoVW) 5 O 14 mixed oxide catalyses partial oxidation because of its intermediate C-H activation and oxygen releasing oxygen functionalities. However, these (MoVW) 5 O 14 -type industrial oxidation catalysts are heterogeneous and highly complex systems. Their physicochemical characterization also revealed that their chemical bulk and surface compositions vary with thermal activation and oxygen potential. A core-shell model is suggested to describe the active catalyst state, the shell providing a high number of active centers, the core high electronic conductivity and ion mobility. The fact that the surface composition of such catalysts is considerably different from their bulk compositions, most probably implies that the ''molecular structure'' at their surface differs too considerably from their bulk crystal structure. Hence, the posed question about the active catalyst structure and its relation to its catalytic performance cannot unambiguously be explained by the crystallographic structure, but still remains unsolved.

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Catalytic properties of the vanadium-molybdenum oxide system for acrolein oxidation

Cited by 38 publications

References 2 publications

One-step glycerol oxidehydration to acrylic acid on multifunctional zeolite catalysts

One-step glycerol oxidehydration to acrylic acid on multifunctional zeolite catalysts

Oxyfunctionalization of Alkanes

MoVW mixed metal oxides catalysts for acrylic acid production: from industrial catalysts to model studies

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