2007
DOI: 10.1016/j.jaap.2006.11.010
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Catalytic pyrolysis of high density polyethylene in a conical spouted bed reactor

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Cited by 89 publications
(44 citation statements)
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“…The acidity of their active sites and its crystalline microporous structure (textural properties) favor hydrogen transfer reactions and thereby make them suitable for obtaining high conversions of gas at relatively low temperatures, between 350 and 500 °C [11,18,22,[41][42][43][44] . That is, these features allow milder operating conditions (lower temperatures and reaction times) than a thermal pyrolysis [4,25,30,45] . Differences in the catalytic activity of these solids are related to their acidic properties, especially the strength and number of acidic sites.…”
Section: Catalytic Pyrolysismentioning
confidence: 99%
“…The acidity of their active sites and its crystalline microporous structure (textural properties) favor hydrogen transfer reactions and thereby make them suitable for obtaining high conversions of gas at relatively low temperatures, between 350 and 500 °C [11,18,22,[41][42][43][44] . That is, these features allow milder operating conditions (lower temperatures and reaction times) than a thermal pyrolysis [4,25,30,45] . Differences in the catalytic activity of these solids are related to their acidic properties, especially the strength and number of acidic sites.…”
Section: Catalytic Pyrolysismentioning
confidence: 99%
“…In previous papers, the good performance of the CSBR has been proven for the selective production of waxes [32], fuel-like hydrocarbons [33] and monomers [34]. This good performance is a consequence of the solid flow pattern, high heat transfer between phases and the smaller defluidization problems when sticky solids are handled.…”
Section: Introductionmentioning
confidence: 99%
“…The conical spouted bed reactor provides an appropriate contact to avoid this problem, [20] and pyrolysis occurs according to the following stages, as shown in Figure 1 [21]: (i) melting of plastic, which coats the sand particles; (ii) cyclic movement of the sand particles coated by plastic during their devolatilization.…”
Section: Conical Spouted Bed Reactormentioning
confidence: 99%