Catalytic reduction of carbon dioxide by a zinc hydride compound, [Tptm]ZnH, and conversion to the methanol level

Ruccolo, Serge; Sambade, David; Shlian, Daniel G.; Amemiya, Erika; Parkin, Gerard

doi:10.1039/d1dt04156h

Dalton Trans.

2022

DOI: 10.1039/d1dt04156h

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Catalytic reduction of carbon dioxide by a zinc hydride compound, [Tptm]ZnH, and conversion to the methanol level

Serge Ruccolo

David Sambade

Daniel G. Shlian

et al.

Abstract: The zinc hydride compound, [Tptm]ZnH, is capable of reducing CO2 to the methanol level.

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Cited by 7 publications

References 154 publications

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Convenient Partial Reduction of CO₂ to a Useful C₁ Building Block: Efficient Access to ¹³C‐Labelled N‐Heterocyclic Carbenes

Phillips,

Sapsford,

Csókás

et al. 2024

ChemCatChem

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The selective, transition metal‐free hydrosilylation of CO2 to CH2(OSiEt3)2 has been achieved under mild conditions and in high isolated yields (up to 90%) using Et3SiH and the simple, easily prepared borohydride catalyst Li+[HB(C6F5)3]−. The resulting CO2‐derived bis(silyl)acetal product – whose mechanism of formation has been interrogated through detailed computational and experimental studies – can be rapidly valorized through the facile synthesis of N‐heterocyclic carbenes, via their corresponding imidazolium salts. By using relatively inexpensive, isotopically enriched 13CO2 this protocol can be exploited to prepare NHC isotopologues that are selectively 13C labelled at the key, ligating C2 position. This provides an electronically responsive 13C NMR spectroscopic handle with dramatically enhanced sensitivity which can directly benefit reactivity studies in both organo‐ and organometallic catalysis, where NHC use is ubiquitous.

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Convenient Partial Reduction of CO₂ to a Useful C₁ Building Block: Efficient Access to ¹³C‐Labelled N‐Heterocyclic Carbenes

Phillips,

Sapsford,

Csókás

et al. 2024

ChemCatChem

View full text Add to dashboard Cite

show abstract

Catalytic hydroboration of carbon dioxide and cyclohexyl isocyanate with diimine zinc hydrides

Sokolov,

Skatova,

Moskalev

et al. 2024

Russ Chem Bull

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Synthesis and Structural Characterization of 2,2’-Bipyridine Zinc Formate: Analysis of Formate Bonding and Hydrosilylation of CO2 and Carbonyl Compounds

de la Mora,

Loo,

Yan

et al. 2024

Journal of Organometallic Chemistry

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Catalytic reduction of carbon dioxide by a zinc hydride compound, [Tptm]ZnH, and conversion to the methanol level

Abstract: The zinc hydride compound, [Tptm]ZnH, is capable of reducing CO2 to the methanol level.

Cited by 7 publications

References 154 publications

Convenient Partial Reduction of CO₂ to a Useful C₁ Building Block: Efficient Access to ¹³C‐Labelled N‐Heterocyclic Carbenes

Convenient Partial Reduction of CO₂ to a Useful C₁ Building Block: Efficient Access to ¹³C‐Labelled N‐Heterocyclic Carbenes

Catalytic hydroboration of carbon dioxide and cyclohexyl isocyanate with diimine zinc hydrides

Synthesis and Structural Characterization of 2,2’-Bipyridine Zinc Formate: Analysis of Formate Bonding and Hydrosilylation of CO2 and Carbonyl Compounds

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Catalytic reduction of carbon dioxide by a zinc hydride compound, [Tptm]ZnH, and conversion to the methanol level

Abstract: The zinc hydride compound, [Tptm]ZnH, is capable of reducing CO2 to the methanol level.

Cited by 7 publications

References 154 publications

Convenient Partial Reduction of CO2 to a Useful C1 Building Block: Efficient Access to 13C‐Labelled N‐Heterocyclic Carbenes

Convenient Partial Reduction of CO2 to a Useful C1 Building Block: Efficient Access to 13C‐Labelled N‐Heterocyclic Carbenes

Catalytic hydroboration of carbon dioxide and cyclohexyl isocyanate with diimine zinc hydrides

Synthesis and Structural Characterization of 2,2’-Bipyridine Zinc Formate: Analysis of Formate Bonding and Hydrosilylation of CO2 and Carbonyl Compounds

Contact Info

Product

Resources

About

Convenient Partial Reduction of CO₂ to a Useful C₁ Building Block: Efficient Access to ¹³C‐Labelled N‐Heterocyclic Carbenes

Convenient Partial Reduction of CO₂ to a Useful C₁ Building Block: Efficient Access to ¹³C‐Labelled N‐Heterocyclic Carbenes