Catalytic sugar-assisted transfer hydrogenation with Ru(II), Rh(III) and Ir(III) halfsandwich complexes

Böge, Matthias; Heck, Jürgen

doi:10.1016/j.molcata.2015.07.015

Cited by 3 publications

(3 citation statements)

References 64 publications

(156 reference statements)

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“…Th complexes were used as precursors of acetophenone ATH. The highest ee (68%) was tained with a ruthenium catalyst [110].…”

Section: Asymmetric Transfer Hydrogenation (Ath)mentioning

confidence: 99%

Transition Metal Complexes with Amino Acids, Peptides and Carbohydrates in Catalytic Asymmetric Synthesis: A Short Review

Titova

2024

Processes

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The present review is devoted to the application of transition metal complexes with such ligands as amino acids, peptides and carbohydrates in catalysis. The literature published over the past 20 years is surveyed. Among the distinctive features of these ligands are their versatility, optical activity, stability and availability. Furthermore, depending on the specific synthetic task to be solved, these ligands open up almost infinite opportunity for modification. Largely thanks to their multifaceted reactivity, transition metal complexes with amino acids, peptides and carbohydrates can catalyze most of the known chemical reactions affording optically pure compounds. In this review, the emphasis is placed upon C(sp3)–H activation, cross-coupling and hydrogenation (including traditional hydrogenation in the presence of hydrogen gas and hydrogenation with hydrogen transfer) reactions. The choice is not accidental, since these reactions on the one hand display the catalytic versatility of the above complexes, and on the other hand, they are widely employed in industry.

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“…Th complexes were used as precursors of acetophenone ATH. The highest ee (68%) was tained with a ruthenium catalyst [110].…”

Section: Asymmetric Transfer Hydrogenation (Ath)mentioning

confidence: 99%

Transition Metal Complexes with Amino Acids, Peptides and Carbohydrates in Catalytic Asymmetric Synthesis: A Short Review

Titova

2024

Processes

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“…4a,5,6 In the literature, the reduction of carbonyl compounds is mainly achieved by using hydrides, 7,8 molecular hydrogen 9,10 and transfer hydrogenation. [11][12][13] Today, among the hydrogenation processes, transfer hydrogenation is a more convenient and reliable method because hydrogen production can be easily controlled in the reaction medium. 14,15 More recently, NaBH 4 , 16 LiAlH 4 , 17 MgH 2 , 18 and NH 3 BH 3 (ref.…”

Section: Introductionmentioning

confidence: 99%

“…In transfer hydrogenation reactions, various catalyst systems are used for effective reduction. 13,19,21,22 Active transition metal containing catalysts play an important role in hydrogenation reactions. A large surface area of the catalyst, depending on the type of metal, is favourable to carry out more effective reduction reactions.…”

Section: Introductionmentioning

confidence: 99%

Eco-friendly hydrogenation of aromatic aldehyde compounds by tandem dehydrogenation of dimethylamine-borane in the presence of a reduced graphene oxide furnished platinum nanocatalyst

Göksu

Yıldız

Çelik

et al. 2016

Catal. Sci. Technol.

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Metal–Carbohydrate Interactions/Complexes

Mikata

2017

Encyclopedia of Inorganic and Bioinorganic Chemistry

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This review introduces recent progress related to carbohydrate–metal interactions and carbohydrate‐based metal complexes. Carbohydrates are ubiquitous natural resources with highly diverse and ordered structures that serve as valuable material pools for life science and fine chemicals. In this context, efficient methods for degradation and molecular transformations of natural polysaccharides into useful compounds promoted by metal–carbohydrate interactions have been investigated. Carbohydrate‐bearing metal complexes exhibit several benefits including targeting to specific cells, enhanced cellular uptake, water solubility, and chirality. Such properties of carbohydrate–metal complexes are utilized in chemotherapy, imaging, catalysis, and other material sciences. Platinum and other metal complexes with carbohydrate ligands as anticancer agents, carbohydrate‐based drug candidates against Alzheimer's diseases, and photosensitizers are possible medicinal applications. Fluorescence, magnetic resonance, and radioactivity of carbohydrate‐based metal complexes are frequently used modalities for molecular imaging. In addition, many carbohydrate–metal complexes are used as catalysts in asymmetric synthesis. These attractive properties of carbohydrate–metal interactions and carbohydrate‐conjugated metal complexes will provide new frontiers in material and life sciences in the future.

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Catalytic sugar-assisted transfer hydrogenation with Ru(II), Rh(III) and Ir(III) halfsandwich complexes

Cited by 3 publications

References 64 publications

Transition Metal Complexes with Amino Acids, Peptides and Carbohydrates in Catalytic Asymmetric Synthesis: A Short Review

Transition Metal Complexes with Amino Acids, Peptides and Carbohydrates in Catalytic Asymmetric Synthesis: A Short Review

Eco-friendly hydrogenation of aromatic aldehyde compounds by tandem dehydrogenation of dimethylamine-borane in the presence of a reduced graphene oxide furnished platinum nanocatalyst

Metal–Carbohydrate Interactions/Complexes

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