Catalyzed autoxidation of hydrazine by cobalt(II) 4,4',4'',4'''-tetrasulfophthalocyanine

Hong, Andrew; Chen, Ting Chien

doi:10.1021/es00048a014

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1997

2022

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“…On the other hand, Ichiro Okura et al [ 35 ] reported that the autoxidation of hydrazine occurred with manganese (III)-hematoporphyrin at room temperature, and that has an advantage because of its reactivity for the formation of oxygen coordinated Mn(III)-Hm peroxide adduct [ 36 ]. Andrew P. Hong et al [ 37 ] reported that satisfactory autoxidation of hydrazines occurred using cobalt (II) 4,4′,4″,4‴-tetrasulfophthalocyanine (CoIITSP).…”

Section: Introductionmentioning

confidence: 99%

Autoxidation of 4-Hydrazinylquinolin-2(1H)-one; Synthesis of Pyridazino[4,3-c:5,6-c′]diquinoline-6,7(5H,8H)-diones

et al. 2022

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An efficient synthesis of a series of pyridazino[4,3-c:5,6-c′]diquinolines was achieved via the autoxidation of 4-hydrazinylquinolin-2(1H)-ones. IR, NMR (1H and 13C), mass spectral data, and elemental analysis were used to fit and elucidate the structures of the newly synthesized compounds. X-ray structure analysis and theoretical calculations unequivocally proved the formation of the structure. The possible mechanism for the reaction is also discussed.

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Section: Introductionmentioning

confidence: 99%