2015
DOI: 10.1016/j.jmmm.2014.09.002
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Catechol-derivatized poly(vinyl alcohol) as a coating molecule for magnetic nanoclusters

Abstract: Surface functionalization of superparamagnetic iron oxide nanoparticles (SPIONs) remains indispensable in promoting colloidal stability and biocompatibility. We propose a well-defined and characterized synthesis of a new catechol-functionalized RAFT (reversible addition-fragmentation chain transfer) poly (vinyl alcohol) polymer, which can be anchored onto hydrophobic SPIONs via a one-pot emulsion ligand exchange process. Both single and clustered nanoparticles are obtained and can be separated from each other.… Show more

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Cited by 11 publications
(16 citation statements)
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“…Hetero-functionalized amine-functionalized polyvinylalcohol (PVA) coated AuNPs (NH 2 PVAAuNPs) with af luorescent dye sandwiched between twopolymer layers, silica NPs with fluorescent dye incorporated in the core and PVA-coated SPIONs with af luorescent dye present on the surface, were prepared as described [11][12][13] and the characterization results of the particles are shown in Table 1. NP aggregation and/or dissolution in ALF wasa ssessed after 24 hincubation at 37°C via cryo electron microscopy(CryoEM) (Fig.…”
Section: Results and Interpretationmentioning
confidence: 99%
“…Hetero-functionalized amine-functionalized polyvinylalcohol (PVA) coated AuNPs (NH 2 PVAAuNPs) with af luorescent dye sandwiched between twopolymer layers, silica NPs with fluorescent dye incorporated in the core and PVA-coated SPIONs with af luorescent dye present on the surface, were prepared as described [11][12][13] and the characterization results of the particles are shown in Table 1. NP aggregation and/or dissolution in ALF wasa ssessed after 24 hincubation at 37°C via cryo electron microscopy(CryoEM) (Fig.…”
Section: Results and Interpretationmentioning
confidence: 99%
“…As a second step, the citric acid was exchanged with PVA−phthalimide (5 kDa), with a catechol anchor group 59 synthesized according to a reported proce-dure. 58 Citric acid-coated nanoparticles were added (4.7 mg polymer/mg Fe) to the polymer dissolved in Milli-Q water, and the mixture was sonicated at room temperature overnight. The nanoparticles were subsequently recollected and dialyzed against water for 2 days to remove excess polymer.…”
Section: Experimental Methodsmentioning
confidence: 99%
“…prepared a DOPA‐based PVA hydrogel with pH‐dependent and self‐healing properties through an esterification reaction between PVA and DOPA. Burnand et al . proposed a well‐defined maleimide catechol end‐functionalized PVA with the assistance of a reversible addition–fragmentation chain‐transfer process; this PVA was mounted onto an iron oxide nanoparticle surface to separate the clusters and single nanoparticles.…”
Section: Introductionmentioning
confidence: 73%