In this study, plasma sprayed Al2O3‐Cr2O3 coatings with different contents of graphene nanosheets were prepared for investigating effects of the graphene on microstructure, mechanical properties and wear behavior of the coating. The experimental results showed that graphene increased the porosity and the micro‐hardness of the coating. But excessive graphene decreased the micro‐hardness remarkably. Besides, the anti‐crack initiation and propagation abilities of the coatings with graphene improved significantly. The wear rate of the coatings decreased firstly and then increased with increasing the graphene content. Impressively, the wear rates of the coating with 2.9% graphene decreased by 33.5% and 36.7%, compared with those of the coating without graphene under normal loads of 5N and 15N, respectively. The main wear mechanisms of the coatings with and without graphene are brittle fracture and abrasive wear.This article is protected by copyright. All rights reserved