2010
DOI: 10.1007/s11426-010-4201-y
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Cation-induced assembly of Zn(II), Cd(II) and Hg(II) coordination complexes and DFT calculations to evaluate weak interactions between the helical chains

Abstract: Two new coordination polymers [ZnLI 2 ] ∞ (1) and [CdLI 2 ] ∞ (2) (L: 3,6-di-(1,2,4-triazole-1-yl)-N-hexylcarbazole) were synthesized and their crystal structures were determined by single-crystal X-ray diffraction techniques. Complexes are both constructed with the helical chains along the 2 1 screw axis. The coordination bond, CH···I weak interactions and - interactions play significant roles in constructing their 3D or 2D frameworks. Two different DFT calculations are performed for the weak interactions … Show more

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