Cationic and radical polymerization using a boron–thienothiophene–triphenylamine based D–π–A type photosensitizer under white LED irradiation

Abstract

A donor-π-acceptor type photoinitiator (DMB-TT-TPA), composed of boron-thienothiophene-triphenylamine to be used as a synthesizer under white LED irradiation, was studied for cationic and radical polymerization of mono and difunctional monomers....

High-Performance Thienothiophene and Single Wall Carbon Nanotube-Based Supercapacitor as a Free-Standing and Flexible Hybrid Energy Storage Material

“…The hybrid electrode ( TT-TPA-SWCNT ) is composed of noncovalent modification of SWCNT with a thienothiophene derivative ( TT-TPA ) (Figure ), − without any binding agent. In our previous study, characterization of the TT-TPA-SWCNT hybrid material was examined and clarified through both experimentally and computationally .…”

Thienothiophene-based organic light-emitting diode: synthesis, photophysical properties and application

“…The UV–vis absorption and fluorescence spectra of DMB-TT-TPA ( 8 ) were recorded in THF ( Figure 1 and Table 1 ) [ 38 ]. It showed maximum absorption and emission wavelengths of 411 and 520 nm (excitation at λ max ), respectively, leading to a mega Stokes shift (>100 nm) of 109 nm, which could be explained to be due to a fast relaxation from the excited state to the ground state as a result of a powerful intramolecular energy transfer between the TPA and boron groups through the thieno[3,2- b ]thiophene (TT) core.…”

“… Absorption and emission of DMB-TT-TPA ( 8 ) in THF. Figure 1 was adapted with permission of Institution of Chemical Engineers (IChemE) and The Royal Society of Chemistry from [ 38 ] (“Cationic and radical polymerization using a boron–thienothiophene–triphenylamine based D-π-A type photosensitizer under white LED irradiation”) by A. Suerkan et al, Mol. Syst.…”

Synthesis and characterization of naphthalenediimide-thienothiophene-conjugated polymers for OFET and OPT applications

“…35,36 Due to their π-extended structure, rigid and good electron-delocalized skeleton, thiophene and its derivatives have played significant roles as donor groups in organic electronics. 37–46…”

“…35,36 Due to their p-extended structure, rigid and good electron-delocalized skeleton, thiophene and its derivatives have played significant roles as donor groups in organic electronics. [37][38][39][40][41][42][43][44][45][46] In recent years, various donor-acceptor (D-A) NDI-and thiophene-based polymeric materials have been developed as semiconducting layers in organic field-effect transistors and solar cells. [47][48][49] Organic phototransistors (OPTs) are optically controllable based on three-terminal OFET devices.…”