Cationic gel crystals and amorphous solids of lightly cross-linked poly(2-vinylpyridine) spheres in the deionized aqueous suspension

Fujii, Syuji; Yamashita, Yuma; Nakamura, Yoshinobu; Tsuchida, Akira; Okubo, Tsuneo

doi:10.1007/s00396-014-3228-6

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Cited by 6 publications

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“…Polymers containing heteroatoms are desirable materials for various applications. Pyridine-based synthetic polymers, a class of versatile N-containing polymers as self-assembling and ion-exchange resin materials, have been attracting industrial and scientific interest because of their application in chemical synthesis . Controlling stereoselectivity of the polymerization reaction is an effective approach to improve synthetic polymers.…”

Section: Introductionmentioning

confidence: 99%

Highly Isotactic and High-Molecular-Weight Poly(2-vinylpyridine) by Coordination Polymerization with Yttrium Bis(phenolate) Ether Catalysts

Yang

2016

ACS Catal.

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The poly(2-vinylpyridine) combining highly isotactic (P m = 0.97) and high-molecular-weight (~10 5 g/mol) was obtained for the first time using novel yttrium bis(phenolate) ether catalysts.These catalysts also showed high activity and tolerance to low loadings. Computational studies and kinetic experiments provided a fundamental understanding of the initiation, propagation, and stereocontrol mechanism governing the polymerization reactions mediated by yttrium catalysts.

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Section: Introductionmentioning

confidence: 99%