A collaborative framework by the synergy of Hazard and Operability (HAZOP) process and the Decision-Matrix Risk Assessment (DMRA) in association with safety-color mapping (SCM) is presented, in order to identify critical points and prioritize risks, and also to visualize the occupational safety and health (OSH) situation, at the workplaces (i) of a sour crude-oil processing industry (SCOPI), and (ii) of a measurement and regulatory station (MRS) in a gas transportation system (GTS), situated in Greece. Firstly, the conventional HAZOP analysis is executed in order to identify the potential fault causes of abnormal conditions (deviations) in the plants. The application of the DMRA-modus is valuable to rank the identified risks (hierarchy of risks). In view of the results, both of the HAZOP pattern (for identifying the hazards) and also the DMRA one (for assessing and ranking the risks), SCMs have been derived for the specific workplaces of the SCOPI and the MRS/GTS station, which could be a precious means for safety managers to appraise the urgency of investing limited budgets in measures preventing particular types of deviations, and also protecting the employees.