High-bunch-charge photoemission electron-sources operating in a continuous wave (CW) mode are required for many advanced applications of particle accelerators, such as electron coolers for hadron beams, electronion colliders, and free-electron lasers (FELs). Superconducting RF (SRF) has several advantages over other electron-gun technologies in CW mode as it offers higher acceleration rate and potentially can generate higher bunch charges and average beam currents. A 112 MHz SRF electron photoinjector (gun) was developed at Brookhaven National Laboratory (BNL) to produce high-brightness and high-bunch-charge bunches for the Coherent electron Cooling Proof-of-Principle (CeC PoP) experiment. The gun utilizes a quarter-wave resonator (QWR) geometry for assuring beam dynamics, and uses high quantum efficiency (QE) multi-alkali photocathodes for generating electrons.