2012
DOI: 10.1260/0263-6174.30.8-9.713
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Cavity Design via Entrapment of Tetrapyrrole Macrocycles in Sol–Gel Matrices for Catalytic, Optical or Sensoring Functions

Abstract: The physicochemical and luminescent properties of tetrapyrrole macrocycles, such as the porphyrins (H 2 P) and phthalocyanines (H 2 Pc), were preserved by trapping or bonding these species in silica matrices. The method involved used hydroxy-aluminium tetrasulphophthalocyanine OH(Al)TSPc as a probe to find optimal conditions for the entrapment of tetrapyrrole molecules. This methodology made possible the trapping or fixing of macrocyclic species or their respective complexes in the interior of pores existing i… Show more

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