Cavity Ring-Down Absorption of O₂ in Air as a Temperature Sensor for an Open and a Cryogenic Optical Cavity

Abstract

The A-band of oxygen has been measured at low resolution at temperatures between 90 K and 373 K using the phase shift cavity ring down (PS-CRD) technique. For temperatures between 90 K and 295 K, the PS-CRD technique presented here involves an optical cavity attached to a cryostat. The static cell and mirrors of the optical cavity are all inside a vacuum chamber at the same temperature of the cryostat. The temperature of the cell can be changed between 77 K and 295 K. For temperatures above 295 K, a hollow glass cylindrical tube without windows has been inserted inside an optical cavity to measure the temperature of air flowing through the tube. The cavity consists of two highly reflective mirrors which are mounted parallel to each other and separated by a distance of 93 cm. In this experiment, air is passed through a heated tube. The temperature of the air flowing through the tube is determined by measuring the intensity of the oxygen absorption as a function of the wavenumber. The A-band of oxygen is measured between 298 K and 373 K, with several air flow rates. To obtain the temperature, the energy of the lower rotational state for seven selected rotational transitions is linearly fitted to a logarithmic function that contains the relative intensity of the rotational transition, the initial and final rotational quantum numbers, and the energy of the transition. Accuracy of the temperature measurement is determined by comparing the calculated temperature from the spectra with the temperature obtained from a calibrated thermocouple inserted at the center of the tube. This flowing air temperature sensor will be used to measure the temperatures of cooling air at the input (cold air) and output (hot air) after cooling the blades of a laboratory gas turbine. The results could contribute to improvements in turbine blade cooling design.

Low-Temperature Cavity-Enhanced Spectroscopy with a Diode Laser: Vibration–Rotation Absorption of CO (3ν) at 80 K and CH3C≡C–H (2ν1) at 165 K

“…18 We have used the same technique flowing air into heated open tubes to obtain air temperatures from O 2 spectra. 19,20 To illustrate the use of the CEAS technique at low temperatures, the vibrational-rotational overtone transitions (υ = 0→3) of carbon monoxide (CO) at 295 and 80 K and the acetylenic C-H (υ = 0→2) bond of CH 3 C≡C-H at 293 and 165 K are obtained. The spectra of CO and CH 3 CCH have been used for identification, composition, and temperature determination in the atmosphere of planets and satellites of the outer solar system and interstellar clouds.…”