Cd(II) complexes derived from thiazoline, hydrazide and carbodithioate ligands: synthesis, crystal structures and electrochemical sensing of uric acid

Abstract

Three novel Cd(II) metal complexes 1-3 have been synthesized with different derivatives of thiazoline, hydrazide and carbodithioate. These metal complexes are abbreviated as [Cd (tht) 2 ] n , [Cd (Hpph) 2 ] n and [Cd (mpps) 2 ] n along with their respective ligands Htht, H 2 pph and mpps. The developed metal complexes are characterized using X-ray diffraction (XRD) data and other spectroscopic techniques (Infrared [IR], nuclear magnetic resonance [NMR], ultraviolet-visible [UV-vis] and fluorescence). The polymeric nature of these cadmium complexes have been ascertained by single XRD data. Several significant interactions were also revealed, which aid in the stabilization of these complexes' supramolecular architecture. Comparing complex 2 with complexes 1 and 3, the absorption spectra of complex 2 exhibits a greater λmax.On comparing the fluorescence study of these complexes, complex 2 has a higher fluorescence than complexes 1 and 3. The cyclic voltammetry (CV) approach was employed to detect the electrochemical behaviour of these complexes, as well as the sensing of uric acid (UA) by these complexes via modified glassy carbon electrodes (GCEs). According to the conclusions received by CV study, the modified electrode containing complex 3 has admirable UA electro catalytic activity. This UA electrochemical sensing device offers a low detection limit (0.3 μM), fine linear ranges (30-1500 μM), reasonable sensitivity, and a fast reaction time.

Tunability of Photovoltaic Functions via Halogen Substitution [(Ade)2 CdX4](X = Cl, Br): A Class of Three-Dimensional Organic–Inorganic Hybrid Materials

“…According to this equation, ∆Ep = Epa − Epc = 59/n, E θ = 0.847 V, and ∆Ep = 0.057 V, where ∆Ep = 59/n = 0.056. I pa /I pc = 0.88, which is close to 1, indicating that the electrochemical reaction is reversible, demonstrating that both compounds have good electrocatalytic properties [57][58][59].…”

Electrochemical sensing of 4‐nitrophenol through heteroleptic complexes of Ag(I) and Hg(II) based on 2‐thiazoline‐2‐thiol: Synthesis, crystal structures, and Hirshfeld analysis

“…The d norm surface's red, white, and blue sections, respectively, display near proximity, medium proximity, and minimal proximity to outside atoms. 39,40 The d norm of complex 1 shows some intense red spots suggesting close proximity and stronger interaction with outside atoms (Figure 5a), while the d norm of complex 2 does not show any intense red spot suggesting the presence of only weaker intermolecular interactions or medium proximity of outside atoms (Figure 5b). The nature and kind of intermolecular interactions seen in complexes 1 and 2 have been quantitatively summarized using the 2-D fingerprint plots, which were created by resolving 3-D d norm surfaces of these complexes.…”

Design, synthesis, and structural evaluation of metal complexes of azepane-1-carbodithioate for targeting human breast cancer: investigating cytotoxic activity against the MDA-MB-231 cell line

“…Dithiocarbamates are incredibly adaptable mono-anionic chelating ligands that form stable complexes with the majority of the main group, lanthanide, and actinide elements as well as transition elements. 1–4 They are easily synthesized from primary or secondary amines, and their solubility in organic solvents or water varies depending on the type of cation. Carbon disulfide can be used to produce incredibly water-soluble dithiocarbamates in the presence of a base and a wide variety of secondary and primary amines.…”