2020
DOI: 10.1016/j.cej.2019.122431
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Ce(III) nanocomposites by partial thermal decomposition of Ce-MOF for effective phosphate adsorption in a wide pH range

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Cited by 225 publications
(79 citation statements)
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“…However, there are several practical drawbacks to using many nanomaterials for large-scale phosphate remediation. In order to treat a problem of this magnitude, the solution must be easily manufacturable, which challenges a number of complex nanostructures (19)(20)(21).…”
Section: A Nanotechnology-based Solution: Advantages and Opportunities For Improvementmentioning
confidence: 99%
“…However, there are several practical drawbacks to using many nanomaterials for large-scale phosphate remediation. In order to treat a problem of this magnitude, the solution must be easily manufacturable, which challenges a number of complex nanostructures (19)(20)(21).…”
Section: A Nanotechnology-based Solution: Advantages and Opportunities For Improvementmentioning
confidence: 99%
“…For all catalysts, first photopeak with the lowest binding energy (BE), observed at 528.5-529.8 eV (� 0.1 eV), was related to O 2À lattice oxygen (noted O I ); this position is close to that reported in the literature. [20,28,29] The second O1s photopeak, observed between 531.8 and 532 eV (� 0.1 eV), was assigned to adsorbed-oxygen species at the surface associated to hydroxyls species OH À (O II ). The third peak observed only for Ce-Au-Amb-Ar with the highest BE, located at 533.5 eV (� 0.1 eV), was related to the surface adsorbed oxygen of physisorbed water (O III ), according to data provided by literature.…”
Section: Xps Resultsmentioning
confidence: 99%
“…Cerium based-catalysts were often used as an adsorbent for the phosphate recovery. Thus, Jiaojie et al [20] reported a good phosphate adsorption capacity (189 mg.g À 1 in final adsorption) with their Ce-MOF metallo-organic framework; while Su et al [21] used CeÀ Zr binary oxide as an efficient nano-adsorbent for phosphates recovery from water with the final phosphates adsorption capacity equal to 112.23 mg.g À 1 . Some ceriumbased materials were studied in catalytic reduction and photocatalytic degradation by oxidation of some large molecule organic pollutants according to, [22,23] their most relevant results show that the cerium oxide choice may be very interesting.…”
Section: Introductionmentioning
confidence: 99%
“…C e /q e = 1/W s a + C e /W s (5) where C e is the equilibrium concentration (mg/L), q e is the amount adsorbed at equilibrium (mg/g), and W s and a are the Langmuir constants related to the monolayer adsorption capacity and the energy of sorption, respectively, and log q e = log k + (1/n) log C e (6) where k and n are the Freundlich constants related to the adsorption of the adsorbent and the intensity of adsorption, respectively. Table 3 exerts the Langmuir and Freundlich constants for the phosphate ion adsorption.…”
Section: Effect Of Contact Time On the Adsorption Of Phosphate Ionmentioning
confidence: 99%
“…Interestingly, metal (hydr)oxides have been considered useful for adsorbing phosphate ion from aquatic ecosystems, owing to their unique physicochemical properties and nontoxic characteristics. [5][6][7] In addition, calcined metal (hydr)oxides are promising adsorbents for the removal of the phosphate ion because they possess a permanent, positive layer charge (and a high specific surface area) 8,9) or a unique memory effect property. 10) The unique memory effect property facilitates rebuilding of the original structure when placed in contact with anions in aqueous solution.…”
Section: Introductionmentioning
confidence: 99%