“…Complex transition-metal oxides have attracted considerable attention by the scientific and engineering communities because of their electrical, magnetic and optical properties which can be used for the development of various new concept devices, energy harvesting, electrical and chemical sensors, etc. [1][2][3][4][5][6][7]. Recently, much attention is focused on oxygen deficient perovskite cobaltates LnBaCo 2 O 5+δ (Ln=Y and Lanthanide) due to their important and unique physical properties, such as high chemical stability, good oxygen permeability, and mixed electronic and ionic conductance at high temperature range (500 o C-700 o C), which makes it one of the best candidates for energy conversion, catalysis, sensing materials, solid oxides fuel cells etc.…”