CeF₃ single crystals for UV‐VIS‐IR optical isolators

Abstract

Optical isolators (OIs) are needed to protect laser sources from back‐reflections. Driven by the fast‐growing market of laser marking and machinery, and the increasing cost of rare‐earth‐based permanent magnets, single‐crystalline Faraday rotators (FRs) with a large Verdet constant V are highly desired to reduce the cost and size of OIs. Furthermore, the need for finer laser procedures (marking, cutting, welding) is shifting the used laser emissions toward shorter wavelengths: into the visible (VIS), where standard Tb3Ga5O12 (TGG) has a poor transmittance, and even into the ultraviolet (UV), where TGG possesses overlapping Tb 4f‐4f absorption bands. In recent years CeF3 has emerged as a new FR with a unique transmittance and an outstanding V in the UV wavelength region, and a superior figure‐of‐merit in the VIS range compared to TGG. Recently, its small thermal lensing and high damage threshold for high‐power have been demonstrated, exhibiting optical isolation > 30 dB under 600 W @ 1070 nm. This review first summarizes the basic properties and crystal growth of CeF3, then focuses on its Faraday magneto‐optical performance. Last but not the least, the typical crystal defects encountered during the development of CeF3 are discussed.

Structure and Magnetic and Magneto-Optical Properties of a New Cubic Ce3Sc2Ga3O12 Garnet Crystal with Heavy Ce3+ Concentration

“…19 So, having a higher Ce ion concentration is a significant challenge for designing materials with a strong magneto-optical effect. On the other hand, the reported high Ce 3+ -containing magneto-optical crystals, such as CeAlO 3 , 18 NaCe(WO 4 ) 2 , 20 NaCe(MoO 4 ) 2 , 21 and CeF 3 , 22,23 are not cubic symmetry. Their birefringence effect leads to difficulties in precisely processing and assembling crystals for magneto-optical devices.…”