CeO2 quantum dots embedded in 3D hierarchical porous foliaceous N-doped carbon as an efficient oxygen reduction electrocatalyst for metal-air battery

Liu, Yisi; Zhang, Yafei; Chen, Zhicheng; Li, Zongxu; Pan, Qing; Du, Yue; Li, Wenzhang; Li, Jie

doi:10.1016/j.jallcom.2022.164063

Cited by 6 publications

(5 citation statements)

References 58 publications

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“…The G band corresponds to the ordered sp 2 -hybridized carbon atoms, while the D band is associated with the disordered graphite structure. 49,50 The intensity ratio of I D / I G = 1.01, reflecting that the carbon material was partially graphitized.…”

Section: Resultsmentioning

confidence: 99%

Shaddock peel-loaded CeO₂ composites with peroxidase-like activity for dye degradation and trace detection of ascorbic acid

Lv,

Gao,

et al. 2024

New J. Chem.

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Section: Resultsmentioning

confidence: 99%

Shaddock peel-loaded CeO₂ composites with peroxidase-like activity for dye degradation and trace detection of ascorbic acid

Lv,

Gao,

et al. 2024

New J. Chem.

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“…The anode is usually made by metals with negative electrode potentials, e.g., lithium, zinc, aluminum, magnesium, iron, etc. [304][305][306] During the discharge process, the anode goes through an oxidation reaction to lose electrons to generate metal ions (Equation ( 51)). The electrons migrate to the cathode by an external circuit, and oxygen goes through an ORR process with water and electrons via the air cathode catalyst to generate hydroxide ions (Equation ( 52))…”

Section: Metal-air Batteriesmentioning

confidence: 99%

“…Development of efficient QDs-containing catalysts for ORR is highly appreciated for the industrial application of Al-air batteries. Liu et al [305] fabricated CeO 2 QDs decorated on foliaceous N-doped carbon with micropores and mesopores. Compared with Pt/C, the obtained catalyst demonstrated remarkable electrocatalytic ORR activity and improved durability.…”

Section: Metal-air Batteriesmentioning

confidence: 99%

Semiconducting Quantum Dots for Energy Conversion and Storage

Huang

2023

Adv Funct Materials

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Semiconducting quantum dots (QDs) have received huge attention for energy conversion and storage due to their unique characteristics, such as quantum size effect, multiple exciton generation effect, large surface‐to‐volume ratio, high density of active sites, and so on. However, the holistic and systematic understanding of the energy conversion and storage mechanism centering on QDs in specific application is still lacking. Herein, a comprehensive introduction of these extraordinary 0D materials, e.g., metal oxide, metal dichalcogenide, metal halides, multinary oxides, and nonmetal QDs, is presented. It starts with the synthetic strategies and unique properties of QDs. Highlights are focused on the rational design and development of advanced QDs‐based materials for the various applications in energy‐related fields, including photocatalytic H2 production, photocatalytic CO2 reduction, photocatalytic N2 reduction, electrocatalytic H2 evolution, electrocatalytic CO2 reduction, electrocatalytic N2 fixation, electrocatalytic O2 evolution, electrocatalytic O2 reduction, solar cells, metal‐ion batteries, lithium–sulfur batteries, metal–air batteries, and supercapacitors. At last, challenges and perspectives of semiconducting QDs for energy conversion and storage are detailedly proposed.

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“…Mesoporous materials may aid in mass/ electron transport during the catalytic process; micropores anchored active sites and encouraged uniform distribution. [118]…”

Section: Metal Oxide Carbon Composite-based Electrocatalystmentioning

confidence: 99%

A Mechanistic Overview of the Current Status and Future Challenges in Air Cathode for Aluminum Air Batteries

Islam

Nayem

Anjum

et al. 2023

The Chemical Record

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Aluminum air batteries (AABs) are a desirable option for portable electronic devices and electric vehicles (EVs) due to their high theoretical energy density (8100 Wh K−1), low cost, and high safety compared to state‐of‐the‐art lithium‐ion batteries (LIBs). However, numerous unresolved technological and scientific issues are preventing AABs from expanding further. One of the key issues is the catalytic reaction kinetics of the air cathode as the fuel (oxygen) for AAB is reduced there. Additionally, the performance and price of an AAB are directly influenced by an air electrode integrated with an oxygen electrocatalyst, which is thought to be the most crucial element. In this study, we covered the oxygen chemistry of the air cathode as well as a brief discussion of the mechanistic insights of active catalysts and how they catalyze and enhance oxygen chemistry reactions. There is also extensive discussion of research into electrocatalytic materials that outperform Pt/C such as nonprecious metal catalysts, metal oxide, perovskites, metal‐organic framework, carbonaceous materials, and their composites. Finally, we provide an overview of the present state, and possible future direction for air cathodes in AABs.

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CeO2 quantum dots embedded in 3D hierarchical porous foliaceous N-doped carbon as an efficient oxygen reduction electrocatalyst for metal-air battery

Cited by 6 publications

References 58 publications

Shaddock peel-loaded CeO₂ composites with peroxidase-like activity for dye degradation and trace detection of ascorbic acid

Shaddock peel-loaded CeO₂ composites with peroxidase-like activity for dye degradation and trace detection of ascorbic acid

Semiconducting Quantum Dots for Energy Conversion and Storage

A Mechanistic Overview of the Current Status and Future Challenges in Air Cathode for Aluminum Air Batteries

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CeO2 quantum dots embedded in 3D hierarchical porous foliaceous N-doped carbon as an efficient oxygen reduction electrocatalyst for metal-air battery

Cited by 6 publications

References 58 publications

Shaddock peel-loaded CeO2 composites with peroxidase-like activity for dye degradation and trace detection of ascorbic acid

Shaddock peel-loaded CeO2 composites with peroxidase-like activity for dye degradation and trace detection of ascorbic acid

Semiconducting Quantum Dots for Energy Conversion and Storage

A Mechanistic Overview of the Current Status and Future Challenges in Air Cathode for Aluminum Air Batteries

Contact Info

Product

Resources

About

Shaddock peel-loaded CeO₂ composites with peroxidase-like activity for dye degradation and trace detection of ascorbic acid

Shaddock peel-loaded CeO₂ composites with peroxidase-like activity for dye degradation and trace detection of ascorbic acid