“…Surface morphologies of the coatings after immersion tests in a 3.5 wt % NaCl solution can be used to evaluate the anticorrosion abilities. − After immersion tests in 3.5 wt % NaCl solution, the superhydrophobic surface of the pure SiO 2 coating (Figure a) is severely corroded and particles and micropores are observed on the surface of SiO 2 coating. The coating gradually loses its protective effect.…”
Coatings with only passive protection cannot offer long-term anticorrosion on metals. Eco-friendly sustainable and responsive coating for active/passive corrosion protection is desirable to extend the service life of metals. Here, benzotriazole (BTA)-metal organic frameworks (Cu-MOFs, UiO-66) were embedded in silica (SiO 2 ) coating by one-step electrodeposition on copper. Combined with passive capability of MOFs and active protection of BTA inhibitor, the composite coating (BTA-MOF/ SiO 2 ) exhibited high and stable corrosion resistance, confirmed by microstructure characterizations and electrochemical tests. As a result, the as-prepared composite coating exhibited superhydrophobicity with a water contact angle of 154.2°. With loading of BTA-MOF in SiO 2 coating, the impedance modulus at 0.01 Hz increased by ∼10-fold and the corrosion current density decreased to 3.472 × 10 −9 A•cm −2 . Immersion and salt spray tests confirmed the long-term protection of the composite coating. The responsive release of BTA inhibitor endows the coating with a responsively anticorrosive behavior. The active-passive ability makes the coating a good candidate for protection on metals used in highly salty environments.
“…Surface morphologies of the coatings after immersion tests in a 3.5 wt % NaCl solution can be used to evaluate the anticorrosion abilities. − After immersion tests in 3.5 wt % NaCl solution, the superhydrophobic surface of the pure SiO 2 coating (Figure a) is severely corroded and particles and micropores are observed on the surface of SiO 2 coating. The coating gradually loses its protective effect.…”
Coatings with only passive protection cannot offer long-term anticorrosion on metals. Eco-friendly sustainable and responsive coating for active/passive corrosion protection is desirable to extend the service life of metals. Here, benzotriazole (BTA)-metal organic frameworks (Cu-MOFs, UiO-66) were embedded in silica (SiO 2 ) coating by one-step electrodeposition on copper. Combined with passive capability of MOFs and active protection of BTA inhibitor, the composite coating (BTA-MOF/ SiO 2 ) exhibited high and stable corrosion resistance, confirmed by microstructure characterizations and electrochemical tests. As a result, the as-prepared composite coating exhibited superhydrophobicity with a water contact angle of 154.2°. With loading of BTA-MOF in SiO 2 coating, the impedance modulus at 0.01 Hz increased by ∼10-fold and the corrosion current density decreased to 3.472 × 10 −9 A•cm −2 . Immersion and salt spray tests confirmed the long-term protection of the composite coating. The responsive release of BTA inhibitor endows the coating with a responsively anticorrosive behavior. The active-passive ability makes the coating a good candidate for protection on metals used in highly salty environments.
“…Here, the reversible conversion of Ce ions, that is shifting from C 3+ to C 4+ , resulted in the formation of Ce oxide/hydroxide precipitates that played a vital role in the defense mechanism and prohibited the corrosion process. The self-defense mechanism of the Ce layer is very efficient, irrespective of its placement in the coating, as Pereira et al further elaborated the effect of the Ce layer, deposited underneath the hybrid duplex CeP-Hyb coating, on WE43 Mg alloy. They tested the active protection of Ce compounds by calculating local EIS in the mapping mode (LEIM) test, where the response of the CeP-Hyb coating was recorded in the response of an artificial defect.…”
Section: Applications and Prospects Of Ln Elementsmentioning
confidence: 99%
“…(d) AFM analysis (e) POL analysis of bare WE43C-T5Mg alloy, CeP coatings, hybrid coatings, and combination of CeP + hybrid coatings. [Reprinted with permission from ref . Copyright 2022, Elsevier].…”
Section: Applications and Prospects Of Ln Elementsmentioning
Lanthanides (Ln), as an important class of materials, have recently generated global interest in modern technology due to their unique metallurgical, ceramic, catalytic, electronic, nuclear, and mechanical properties. Here,
“…There is also research and development in magnesium alloys [23,24] especially in industrial applications. There is a study on corrosion prevention of alloys [25] , work on shape memory alloys mainly on engineering applications [26] and applying computer modeling on alloys [27] .…”
Section: Highlights Of Recent Progress On Metalsmentioning
This work briefly describes some of the different features of groups ofmetals. It highlights recent progress in research into metals. It details thestructures and defects in solid metals. The common theories of metalsincluding the free electron theory, band theory, the ions in a sea ofelectrons model and the soft sphere model are discussed and their meritsare considered. It describes distinctions between the bonding in metalsand inter-metallic compounds. It shows the influence of bonding on theproperties of metals and alloys and provides a summary of tradition andnewer uses of metals.
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