[CF3Au(C.tplbond.NMe)] as a precursor for CVD of gold

[Au(CF3)(CO)]: A Gold Carbonyl Compound Stabilized by a Trifluoromethyl Group

“…[35] The methyl derivative [Au(CH 3 )(CO)] would also be expected to be substantially less stable than 2, given the lower stability of the related species [Au(CH 3 )(CNMe)] with respect to its fluorinated homologue [Au(CF 3 )(CNMe)]. [36] The isolation of [Au(CF 3 )(CO)] (2) underlines the importance of gold carbonyl derivatives as intermediate species in the preparation of Au NPs. Preliminary results reveal that the CO molecule in 2 can be readily replaced by a number of other ligands.…”

Facile Synthesis and Characterization of New β‐Diketonate Silver Complexes. Single‐Crystal Structures of (1,1,1,5,5,5‐Hexafluoro‐2,4‐pentadionato)(2,2′‐bipyridine)silver(I) and (1,1,1,5,5,5‐Hexafluoro‐2,4‐pentadionato)(N,N,N′,N′‐tetramethylethylenediamine)silver(I) and Their Use as MOCVD Precursors for Silver Films

“…Nitrogen was used as the carrier gas, while the reacting gas (hydrogen or nitrogen/water vapor mixture) was introduced to the main flow in the vicinity of the reaction zone after the furnace temperature was reached. In order to introduce H 2 O into the reaction atmosphere, nitrogen was bubbled through a distilled water reservoir (50 cm 3 ) kept at room temperature. In these conditions, the amount of water released was 5 g h ±1 determined by measuring its mass before and after the experiment.…”

Synthesis, Potentiometric, Spectral Characterization and Microbial Studies of Transition Metal Complexes with Tridentate Ligand

“…The magnetic and electronic spectral data is given in 6 A 1g → 4 T 1 (G), 6 A 1g → 4 T 2g (G) and 6 A 1g → 4 E g transitions respectively, indicate octahedral geometry of the complex. 30,31 The calculated values of ligand field splitting energy (10 Dq), Racah interelectronic repulsion parameter (B), covalent factor (β), ratio υ 2 /υ 1 and ligand field stabilization energy (LFSE) data of metal complexes given in Table 3 supports the proposed geometry for all the complexes.…”

“…The metal complexes of Schiff bases derived from diamines and heterocyclic compounds have been the centre of attraction for many workers in recent years. [4][5][6][7] Dehydroacetic acid is one of such heterocyclic compound. Literature survey reveals that little attention has been given to tridentate Schiff bases of DHA containing ONN donor systems.…”