Packed beds are widely used in industries and it is of great significance to enhance the heat transfer between gas and solid states inside the bed. In this paper, numerical simulation method is adopted to investigate the heat transfer principle in the bed at particle scale, and to develop the direct enhanced heat transfer methods in packed beds. The gas is treated as continuous phase and solved by Computational Fluid Dynamics (CFD), while the particles are treated as discrete phase and solved by the Discrete Element Method (DEM); taking entransy dissipation to evaluate the heat transfer process. Considering the overall performance and entransy dissipation, the results show that, compared with the uniform particle size distribution, radial distribution of multiparticle size can effectively improve the heat transfer performance because it optimizes the velocity and temperature field, reduces the equivalent thermal resistance of convection heat transfer process, and the temperature of outlet gas increases significantly, which indicates the heat quality of the gas has been greatly improved. The increase in distribution thickness obviously enhances heat transfer performance without reducing the equivalent thermal resistance in the bed. The result is of great importance for guiding practical engineering applications.