Fatty acid methyl
esters are extensively used compounds in the
industry, but they are perhaps most widely known for their application
as biodiesel. In this study, we propose the rotor–stator spinning
disc reactor (RS-SDR) as an intensified reactor for the production
of fatty acid methyl esters. The RS-SDR relies on the generation of
high shear forces in the small gap of a disc, rotating at high speeds,
and a stationary wall, to improve on mass and heat transfer rates.
Here, we have illustrated the benefits of mass transfer intensification
for this reaction by performing the homogeneous base-catalyzed reaction
in both a single-stage and a scaled-up multistage RS-SDR. A high level
of productivity could be obtained in the multistage reactor (7.78
× 103 mol mR
–3 min–1 at a conversion
of 82%). Furthermore, we also performed a heterogeneous transesterification
reaction with calcined sodium silicate as a slurry catalyst. We were
able to obtain a productivity of 214 mol mR
–3 min–1 in the
RS-SDR (72% conversion, with a residence time of 8 min). In comparison,
the batch heterogeneous system had 47% conversion during the same
time period of operation. The high slurry concentrations of up to
20 wt % (based on oil weight fraction) did not lead to clogging or
fouling in the reactor. These results demonstrate the potential of
the RS-SDR for the transesterification reaction.