Environmental, social and governance (ESG) continues to be the most significant risk facing the world in the next decade. Failure in climate change adaptation and mitigation, extreme weather, loss of biodiversity, erosion of social cohesion, livelihood crises and infectious diseases were among the major concerns being highlighted in the recent World Economic Forum's survey. Countries around the globe have been working together to address these risks by responding to the 2030 Agenda for Sustainable Development and continuous monitoring of its 17 goals since September 2015. In a similar vein, there have been many calls for the chief financial officers (CFOs) to lead their organisational journey towards sustainability. The launching of CFO Principles on Integrated SDG Investments and Finance in year 2020 and CFO Coalition for the SDGs recently have cemented the significant role of CFOs in sustainability. In Malaysia, the national accounting regulatory body -Malaysian Institute of Accountants (MIA)have set ESG high on its agenda and it is to be embraced by all its members. Drawing upon upper echelons perspective and resource-based theory, this research presents preliminary evidence on the relationship between CFO characteristics and ESG ratings among public listed companies in Malaysia. Based on the analysis of 252 companies for the year 2022, we observed the influence of CFO professional qualification, ethnicity, and tenure. This research focuses on a topic which has not been extensively investigated by the past researchers. Furthermore, it offers practical implications on matters related to CFOs in ensuring corporate sustainability.