CH3O Substitution Effect Revisited in the Vibrationally Resolved Laser-Induced Fluorescence Spectra of Methoxycyclohexoxy Radicals
Yizhen Zou,
Fengming Yu,
Xiaoyu Liu
et al.
Abstract:The oxy-substituted alkoxy radicals have attracted wide attention due to the increasing application of oxygenated volatile organic compounds as fuel additives and solvents. Direct detection of these intermediate radicals is desired for measuring the reaction rate and investigating the oxidation mechanism of organic compounds in the atmosphere. A charge-transfer excited state induced by CH 3 O substitution was identified in our previous study of 3-methoxy-1-propoxy radical [Xue, J. et al. Phys. Chem. Chem. Phy… Show more
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