2023
DOI: 10.1002/pol.20230748
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Chain trajectories, domain shapes, and terminal boundaries in block copolymers

Benjamin R. Greenvall,
Michael S. Dimitriyev,
Gregory M. Grason

Abstract: The packing geometry of macromolecules in complex mesophases is of key importance to self‐organization in synthetic and biological soft materials. While approximate or heuristic models rely on often‐untested assumptions about how flexible molecules “fit in” to distinct locations of complex assemblies, physical assemblies derive from ensembles of fluctuating conformations, obscuring the connection between mesophase geometry and the underlying arrangements. Here, we present an approach to extract and analyze fea… Show more

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