2024
DOI: 10.1002/asia.202400916
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Chalcogen Bond‐Driven Alkylations: Selenoxide‐Pillar[5]arene as a Recyclable Catalyst for Displacement Reactions in Water

Pâmella Cordeiro,
Victor Menezes,
Alix Y. Bastidas Ángel
et al.

Abstract: A novel strategy to catalyze alkylation reactions through chalcogen bond interaction using a supramolecular structure is presented herein. Utilizing just 1.0 mol% of selenoxide‐pillar[5]arene (P[5]SeO) as the catalyst we achieved efficient catalysis in the cyanation of benzyl bromide in water. Our approach demonstrated high efficiency and effectiveness, with the results supported by designed control experiments and theoretical models, highlighting the catalytic effect of the pillar[5]arene through noncovalent … Show more

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