Resonant conversion of near-infrared (NIR) to visible (VIS) light, so-called upconversion (UC), is one approach to the development of compact and efficient VIS solidstate lasers, which are of most interest in optical storage, display, and medical applications. In contrast to NIR frequency doubling and VIS semiconductor lasers, UC in principle permits high laser power in narrow bands."] UC processes can be observed in many lanthanide-(mainly Er-, Tm-, Pr-, and Ho-) containing dielectric hosts. Because of the structure of the energy levels of lanthanide ions, UC is often based on excited-state absorption (ESA) or energytransfer upconversion (ETU).[21 Up to now, UC lasers have been implemented using lanthanide-doped fluoride and oxide crystals and heavy metal fluoride glass fibers.[31 In the search for new UC laser hosts, glasses that can be drawn into fibers are seen as very attractive materials.Waveguiding fibers guarantee that the exciting NIR radiation has a high density along the entire absorption medium, thereby lowering the laser threshold power. A further advantage is that the long interaction length allows the concentration of the activator ions to be reduced, thereby minimizing concentration quenching and facilitating heat removal. ['] Because of the advantages of the fiber geometry compared to other laser geometries, most progress in UC lasers in the past has been made using UC fluoride glass fibers. Continuous-wave laser action at room temperaturethe most attractive process for the above mentioned applications-was first demonstrated using fluorozirconate (ZBLAN) glassFor the further development of UC fiber materials, emphasis is now placed on the reduction of their phonon energies in order to significantly slow down non-radiative multiphonon relaxation and thus increase UC Phonon energies of dielectric hosts are reduced by introducing heavier anions. In this way, multiphonon losses of fluoridebased glasses were significantly and the UC efficiency of ZrF4-based glasses improved. ['21). In the past, chloride-and bromide-based glasses were investigated because of their high IR transparency, which makes them very attractive for fiber delivery of IR laser light (e.g., C02 laser at 10.6 pm).[13,141 Concentrating on UC, waveguides based on such heavier halides should combine high fluorescence quantum yields with the advantages of the fiber geometry and are expected to facilitate the step from UC luminescence to UC laser action. However, due to the high moisture sensitivity of heavier halide based UC glasses,[''-'s1 no optical fibers only a few micrometers thick have yet been produced.In this paper, we describe the first heavier halide based upconversion fibers. To our knowledge, they are also the first optical waveguides based on a heavier-halide glass to be reported. The fibers are made of a new ZnBr2-containing UC glass and Er3@ as the activator ion. On excitation at 800 and 980 nm, this glass shows bright greenish and turquoise luminescence, respectively. More importantly, using this glass and implementing...