Supercritical
carbon dioxide (scCO2) is considered to
be an excellent candidate for miscible gas injection (MGI) because
it can reduce oil viscosity, induce in situ swelling of the oil, and
reduce the IFT of the in situ fluid system. However, the unfavorable
mobility associated with scCO2 flooding poses a major challenge
due to the large viscosity contrast between the crude oil and scCO2, resulting in viscous fingering. An effective approach to
overcome this challenge is to increase the viscosity of scCO2 (scCO2 thickening) to effectively control gas mobility
and improve the sweep efficiency. The primary focus of this study
was on an oilfield (Field A) that is located in the Harweel cluster
in southern Oman. In this work, we present results in which the suitability
of a library of commercially available polymers capable of thickening
scCO2 at a high temperature (377 K). Previous studies have
focused on the use of polymers as viscosifiers at much lower temperatures.
Out of 26 potential polymers, 4 polymers (poly(1-decene) (P-1-D),
poly(ethyl vinyl ether) (PVEE), poly(iso-butyl vinyl ether) (Piso-BVE),
and poly(dimethylsiloxane) (PDMS)) were found to be completely soluble
in scCO2 at 377 K and 55 MPa. Given the relatively low
viscosity of oil in Field A (0.23 cP), P-1-D and PVEE could be considered
as effective thickeners under the in situ conditions relevant to this
field. In addition, Piso-BVE was found to be less effective because
it did not change the CO2 viscosity above 358 K (55 MPa)
when used at a concentration of 1.5 wt %. Furthermore, although it
was determined that increasing the side chain length of poly alkyl
vinyl ethers would enhance the solubility of this polymer in scCO2, it was determined to be ineffective in noticeably changing
the CO2 viscosity. In general, increasing temperature resulted
in a decrease in the relative viscosity, while increasing the pressure
caused a slight increase in relative viscosity at all temperatures
and concentrations.