Organic light-emitting diodes (OLEDs) are emerging technologies
for potential lighting and display applications. Transparent conductive
electrodes (TCEs) play a crucial role in enabling the functionality
and increased performance of these particular devices. Despite their
widespread use, indium tin oxide (ITO) thin films have several significant
drawbacks, including material scarcity, high costs associated with
both materials and fabrication processes, and limited flexibility.
To address these issues, we thoroughly investigate the deposition
of poly(3,4-ethylenedioxythiophene) (PEDOT) thin films as a promising
alternative to ITO using a single-step and dry method named oxidative
chemical vapor deposition (oCVD). The impact of increasing the substrate
temperature from 110 to 190 °C on the film’s structure
and properties was revealed with an increase in the film conductivity
to over 1600 S/cm at 170 °C and a total transmittance of 97%
in the visible range. This increase was attributed to a change in
the molecular structure of the conjugated polymer from benzoid to
quinoid as revealed by Raman and FTIR measurements. The XPS results
demonstrated an increase in the doping ratio with Cl-containing species
and a reduction of impurities. GIXRD, HR-TEM, and AFM measurements
indicated a smooth surface and a highly face-on orientation for all
temperatures. The optimized TCE layers were successfully integrated
into deep blue OLED devices emitting at 436 nm with stable color Commission
Internationale de l’Energie (CIE) coordinates of (0.15, 0.08)
under variation of the applied current. A satisfactory performance
(72.1 cd/m2 and 0.86 W/sr·m2 at 10 mA cm–2) and an external quantum efficiency (EQE) of 1.04%
were achieved. These results are quite promising, as OLEDs based on
PEDOT as a TCE have demonstrated slightly better output performance
in terms of luminance and radiance, with an increase in EQE by a factor
of 1.7, compared to the reference device based on ITO.